弛豫铁电体结构起伏与弛豫性研究StructuralFluctuationand.PDF

2005 年第 63 卷 化 学 学 报 Vol. 63, 2005 第 12 期, 1095～1099 ACTA CHIMICA SINICA No. 12, 1095～1099 ·研究论文· 弛豫铁电体结构起伏与弛豫性研究 张栋杰*,a 姚 熹 b (a 南京师范大学材料科学重点实验室 南京 210097) (b 西安交通大学电子材料与元器件研究所 西安 710049) 摘要 制备了铅基弛豫铁电体 0.9Pb(Mg Nb )O -0.1PbTiO 和 Pb(Zn Nb )O 基陶瓷. 铅基弛豫铁电体 PMNT, PZN 1/3 2/3 3 3 1/3 2/3 3 基陶瓷弛豫过程可用局域冻结模型描述. 在微畴-宏畴转变过程中, 弛豫铁电体产生结构起伏; 在相同的频率条件下, 弛豫铁电体的结构起伏程度越大, 弛豫程度越低. 在微畴-宏畴转变过程中, 随微畴的增大, 弛豫铁电体的弛豫特性减 弱或消失. 关键词 铁电体; 弛豫; 结构; 畴 Structural Fluctuation and Relaxation of Perovskite Relaxor Ferroelectrics ZHANG, Dong-Jie*,a YAO, Xib a ( Laboratory of Materials Science , Nanjing Normal University, Nanjing 210097) (b Electronic Materials Research Laboratory, Xi ′an Jiaotong University, Xi ′an 710049) Abstract The Pb-based complex perovskite relaxor ferroelectrics (RFE) of PMN and PZN ceramics were prepared. The microdomain-macrodomain transition of relaxor ferroelectrics was investigated by conven- tional method deeply by using amending local freezing glass-model. The structural fluctuation has taken place in RFE during the microdomain-macrodomain transition. The larger the structural fluctuation of RFE was, the lower the relaxation degree was in the same frequency conditio