低甲醛释放脲醛树脂胶粘剂研究进展 - 林产化学与工业.pdf

24 2 Vol.24 No.2 2004 6 Chemistry and Industry of Forest Products June 2004 * 闫 冰, 欧义芳, 曹德榕 , 马志君 ( 中科院广州化学研究所纤维素开放研究实验室, 广东 广州510650) YAN B : , , : ; ; :TQ433. 431 :A :0253- 2417(2004) 02- 0097- 05 RESEARCH PROGRESS ON REA-FORMALDEHYDE ADHESIVE OF LOW FORMALDEHYDE EMISSION YAN Bing, O Y-i fang, CAO De-rong, MA Zh-i jun ( Guangz hou Institute of Chemistry , Chinese Academy of Sciences, Guangz hou 510650, China ) Abstract: Recent researches on the mechanisms on synthesis, curing and formaldehyde emission of F adhesive are reported.Some measures such as reducing the toxicity of F resins,improving the adhesive strength,water resistance and an- ti-ageing property of F resins are also summarized.Attentionswere paid to the mechanisms of the modified process during preparation and after curing of the resin. Key words: formaldehyde; F resins; mechanism ( F) ,, [ 1] [2] F Tollens B , 1929IG F Kanrit Leim , , ,, ,, [2] , , 1 1. 1 :2003- 03- 17 : ( 1979- ) , ,,, * 98 24 , , ; , , : , pH pH 5~ 8 ,, pH [3] pH 2~ 3 , , 3 ,3, 5- - - 1,4 ( uron) , , ,, ,, ; [4] ,, , [ 5] ,, , [ 6] , [ 7] [8~ 10] 20 80 ,Willimas ,Gu J Y