物理学-扫描隧道显微镜在单分子科学中的应用（The application of the physics - scanning tunneling microscope in monolecular science）.docVIP

物理学-扫描隧道显微镜在单分子科学中的应用（The application of the physics - scanning tunneling microscope in monolecular science） Pick to single molecular science is a new cross science, is of great significance in the current development of science and technology. Scanning tunneling microscopy (STM) is the study of single molecule of a strong and unique tools. Based on the authors research group in recent years in single molecular characterization, control, and research progress in aspects of prototype components to design as an example, summarizes the application of scanning tunneling microscopy (STM) in single molecule science, focus on the following results: the mercaptan molecular self-assembly monolayer membranes observed eigen cage structure of C60 molecule, and found a novel topology sequence produced by C60 molecule orientation; Combining experimental images and theoretical simulation, the adsorption orientation of single C60 molecules in Si (111) \ | 7 x 7 surface was determined. The position and orientation of the relative carbon cage of metal atoms were determined by the space and energy resolution imaging and related theoretical simulation of the metal fullerenes molecular Dy @ C82. The molecular operation of a single CoPc molecule adsorbed on the surface of Au (111) by scanning tunneling microscope is used to realize the quantum control of its adsorption state and spin state. A new rectifying mechanism of the special level structure of the single electron tunneling and C59N molecules is found. Found a by needlepoint electronic state and CoPc Co atomic orbitals symmetry of space matching the negative differential resistance effect.  Keyword scanning tunneling microscopy, single molecular science, single molecular characterization, spin state regulation and single molecular devices    1 introduction  In recent years, single molecular science has gradually developed into a dramatic and broad prospects for new type of interdisciplinary, received the attention of many rese