风化煤中腐殖酸的提取及其性能表征 - 环境工程学报.pdf

第 11卷　 第5 期 环 境 工 程 学 报 Vol. 11,No.5 2 0 1 7 年 5 月 Chinese Journal of Environmental Engineering May 2 0 1 7 风化煤中腐殖酸的提取及其性能表征 ∗ 郭雅妮 ,马畅柠,惠璠,杨靖,王理明 西安工程大学环境与化学工程学院,西安 710048 摘　 要　 以陕西黄陵风化煤为原料,分别采用碱溶酸析、氧解法和催化法提取腐殖酸,确定提取的最佳工艺条件,并通过测 定腐殖酸灰分、红外光谱、凝胶色谱和E / E 值对提取的腐殖酸进行性能表征,考察不同的提取方法对腐殖酸的提取率及4 6 结构的影响。 结果显示,3 种方法制备的腐殖酸在官能团结构方面没有明显的差异,腐殖酸中含有大量的—COOH 和—CO 官能团;催化法提取的腐殖酸灰分最多,分子量最大。 实验得到最佳提取腐殖酸的实验方法为催化法,最佳提取工艺为催 -1 化剂选用 NHPI、1∶8 的固液比、0.5 mol ·L NaOH碱液和30 min 的沸水浴时间。 关键词　 风化煤;腐殖酸;提取;表征 中图分类号　 X705　　 文献标识码　 A　　 文章编号　 1673-9108(2017)05-3153-08　　 DOI　 10.12030/ j.cjee.201601216 Humic acid extraction from weathered coal and its properties characterization ∗ GUO Yani ,MA Changning,HUI Fan,YANG Jing,WANG Liming College of Environment and Chemical Engineering,Xi′an Polytechnic University,Xi′an 710048,China Abstract　 By using Huangling weathered coal from the Shaanxi province as the raw material,humic acid from weathered coal was extracted through alkali soluble acid,oxygen,and catalytic methods and the optimum process for humic acid extraction was determined. The properties of humic acid were characterized through ash analyses, infrared chromatography,gel chromatography,andE / E value determinations. The influence of different extrac- 4 6 tion methods was assessed in terms of the yield and structure of the humic acid. The results revealed that there were no significant differences in the humic acid functional groups after the raw material was treated with the three extraction methods, and all products contained large numbers of —COOH and —CO functional groups. The ash content was the highest and the molecular weight of humic acid was the largest in the product produced with the catalytic method. The catalytic method was found to be optimal for the extrac