金,银,铂,钯合金中钯的选择性滴定方法的研究与应用.pdf

2007 5 May 2007 28 2 Precious Metals Vol. 28, No. 2 1 2 1 1 1 ( 1. 650221 2. 650228 ) EDTA-Pd EDTAPb(NO ) 3 2 Pd Pd 2 Pd 5~30mg Pd-0.17% ~ +0.20% AuAgPtPd 5%~99%Pd O655.2 A 1004-0676(2007)02-0040-05 Research and Application of the Method for Selective Titration of Pd in Au, Ag, Pt, Pd Alloys 1 2 1 1 1 ZHU Liya , ZHAO Yining , JIN Yaqiu , DUAN Ying , AN Zhongqing (1. Kunming Institute of Precious Metals, Kunming, Yunnan 650221, China; 2. Kunming Institute of Standardization, Kunming, Yunnan 650228, China ) Abstract: A new method for determination of Pd using precipitation separation by butanedione dioxime as a selective reagent and complexometic titration EDTA released from EDTA-Pd complex was established. The conditions of determination Pd in HNO3 or HCl medium were studied systematically. The proposed method was also compared with the analytical method inNational Standard. Research results indicated that there is no significant difference between the two methods on accuracy, the relative error of the new method is -0.17% ~ +0.20% for Pd content from 5~30mg. But the new method possesses excellent selectivity, suitability, and fast operation, easy to handle. It has been used to determine of Pd from 5%~99% in Au, Ag, Pt, Pd alloys with satisfactory results. Key words: analytical chemistry; titration; butanedione dioxime ;Au alloys; Ag alloys; Pt alloys; Pd alloys; Pd AuAgPtPd