不同辐照剂量壳聚糖酰化改性产物的结构和性质比较.pdfVIP

现代食品科技 Modern Food Science and Technology 2016, Vol.32, No.6 不同辐照剂量壳聚糖酰化改性产物的 结构和性质比较 崔文慧，郭芹，李庆鹏，李咏富，靳婧，哈益明 （中国农业科学院农产品加工研究所/农业部农产品加工与质量控制重点开放实验室，农产品贮藏保鲜与物流研 究室，北京 100193） 摘要：将不同辐照剂量的壳聚糖进行酰化改性，然后分别测定改性前后壳聚糖水溶性和粘度，并通过傅里叶红外光谱仪 （FT-IR ）、热重-差热综合分析仪（TG/DTA ）、粉末X-衍射仪（XRD ）和电子扫描电镜仪(SEM)对其结构进行表征。结果表明：辐 照剂量越大，壳聚糖酰化改性产物产率越低；与壳聚糖相比，未辐照的酰化改性后壳聚糖水溶性和分子量大大增加，粘度明显下 降；而随着辐照剂量的增加，经过辐照的酰化改性后壳聚糖水溶性和分子量没有明显的变化，粘度明显降低。FT-IR 和TG/DTA 图表 明酰化改性后壳聚糖分子中成功引入了亲水基团（羧基），XRD 和 SEM 图分别显示酰化改性后壳聚糖晶体结构被破坏，呈现疏松多 孔结构，改性后壳聚糖的结构更有利于水分子的进入。结构决定性质，结构变化必然引起性质的变化。进行壳聚糖酰化改性产物结 构和性质的比较，对壳聚糖的进一步应用具有理论参考价值。 关键词：壳聚糖；辐照剂量；酰化改性；壳聚糖-柠檬酸；性质；结构表征 文章篇号：1673-9078(2016)6-77-84 DOI: 10.13982/j.mfst.1673-9078.2016.6.013 Structures and Properties of Chitosan Acylation Products after Irradiation with Different Doses CUI Wen-hui, GUO Qin, LI Qing-peng, LI Yong-fu, JIN Jing, HA Yi-ming (Agro-products Processing and Quality Control Key Laboratory of Ministry of Agriculture/Institute Agro-products Processing Science and Technology Chinese Academy of Agricultural Science, Beijing 100193, China) Abstract: Chitosan samples irradiated with different doses were modified by acylation, and then their water solubility and viscosity were determined. In addition, the structures of acylated products were characterized by Fourier transform infrared spectroscopy (FTIR), thermogravimetric/differential thermal analysis (TG/DTA), powder X-ray diffraction (XRD) and scanning electron microscopy (SEM). The results indicated that t