电纺PAN 纳米纤维的碳化工艺研究.PDF

2007 353 # 25 # PAN 1 , Javed Rafique, ( , 518055) : (PAN) / (TG/ DTA) ,, 290 e PAN , 930 e , ( SEM) Ra an PAN ,PAN : ; ; ; ; ; A Study on Car bon ization of PAN Nanofib er s Prep ar ed by Electr ospinnin g YU J i2lia ng , JA VED Raf ique, YU J i e (Depart ent of Material Science and Engineering, Harbin Institute of Technology Shenzhen Graduate School, Shenzhen 518055, China) Abst ract : Thepolyacrylonitrile (PAN) nanofiberswaspreparedby electrospinning. This carbonization tech2 nique was studyed. Ther ogravi etry/Differential Ther al Analysis (TG/DTA) were carried out for the PAN nanofibers in air and nitrogen respectively. It was foundthat theoxidization ofthe PAN nanofibers occurs290 e , and the PAN nanofibers wereco pletely carbonized at 950 e . The structures of the carbon nanofibers obtained by different experi ental process were characterized by scanning electron icroscope (SEM) and Ra an spec2 troscopy. The processes of oxidization and carbonization for the electrospun PAN nanofibers were well estab2 lished. Key words: electrospinning; PAN; TG/DTA; SEM; Ra an; carbon nanofibers (Electrospinning)(~ ) , [1] (50~ 500 n ) : [2] 1934 For als : US, US 1975504, , [3,4] 1934 (:) , ; , [5,6] [7] : [8,9] :(1) , ; (2) , , , ;(3) , ; ,