过渡金属氧化物触媒应用于锌–空气燃料电池阴极之研究.PDF

金 料 林 立料 金 料 量 料便諸 類 率 了 來車 ( 率) 量 / 率 ()行 (O H OOH )(OH HO ) 類 2 2 2 量廉理行量 金 ACP 列 金 La-Ca-Co-O Y-Ba-Cu-O Ba-Ru-O Co-O Cu-O Ru-O 利 H O 2 2 I 350Y-Ba-Cu-O 料 60wt% 40wt%PTFE 60wt% 20wt% 20wt%PTFE 利 流 Tafel 不行 流Co3O4 RuO2 CuO 350 行Tafel 不易理論 力路 0.3~0.65V II A Study on the Transition-metal Oxide Catalysts for the Cathode of Zinc-Air Fuel Cell Student Ya-Jean Huang Adviser Dr. Pang Lin Department of Material Science and Engineering National Chiao Tung University Abstract Metal-air fuel cells include the Zn-air and Al-air type fuel cells. They have been used as low-power portable electronics, because of their simple structure, high specific energy, low cost, stability and other advantages. To meet the future energy requirements of electrical motorcycles in this country, the cathode activities of the zinc-air fuel cells (or the reduction rate of O2) should be boosted to a high specific energy/power. The reduction mechanism of O2 in alkaline media prevails on the surfaces of conductive powders (e.g. carbon black loaded with an electrocatalyst) mixed in t