论文-AZ63镁合金晶粒细化.docVIP

LANZHOU UNIVERSITY OF TECHNOLOGY 题 目 AZ63镁合金晶粒细化 学生姓名 秦宝宏 学 号 专业班级 材控（3）班 指导教师 陈体军 学 院 材料科学与工程 答辩日期 2012年6月 摘 要 近年来，随着汽车制造、航空航天、通讯、光学仪器和计算机领域的飞速发展，镁合金作为一种理想的工业材料倍受世人关注，被认为是二十一世纪最具有应用和开发前景的商用轻质材料。镁合金的开发应用，已成为当今材料领域研究的热点，具有巨大的应用潜力，而且半固态成形被认为是镁合金最有发展前途的新型成形技术。然而，铸态镁合金组织比较粗大，严重影响其机械性能，同时影响半固态锭料的组织。对于含铝镁合金，碳孕育是目前最有效的晶粒细化手段。本文从形核和生长的角度探讨了细化机理,研究了MgCO3、SiC对AZ63镁合金微观组织的影响。 结果表明：MgCO3和SiC对AZ63镁合金组织都有细化作用。主要机理是细化剂与合金元素反应生成A14C3，A14C3与a-Mg均为六方晶系，且晶格常数相近，因此可作为a-Mg原子的非均质形核的基底，一部分C元素因溶质再分配而富集到晶间，反应生成点状A14C3，对晶粒的生长起到阻碍作用，从而使晶粒细化。另外，SiC加入后，反应生成的Mg2Si对晶粒的生长也起到阻碍作用。 AZ63镁合金经过MgCO3、SiC处理后组织明显得到了细化。相比而言，SiC处理的细化效果衰退现象比较弱，且比MgCO3的细化效果稳定，可操作性、可靠性强。 关键词: AZ63镁合金；晶粒细化；细化机理；MgCO3 、SiC Abstract In recent years, as automobile manufacture, aviation, communication, optical instrument and the rapid development of the computer field, magnesium alloys as a kind of ideal industrial materials much attention, and is considered the 21-st century most has the prospects of the application and development of commercial lightweight materials. For the development and application of magnesium alloy, has become the focus of research material field, has great potential applications, and semi-solid forming is considered the most promising new magnesium alloys forming technology. However, as-cast magnesium alloy organization is bulky, the serious influence its mechanical properties, and influence of semi-solid pounds material organization. For including aluminium magnesium alloy, carbon inoculation is one of the most effective means of the grains will be refined. This paper, from the nucleation and growth perspectives detailing the mechanism, the MgCO3, SiC AZ63 magnesium alloys of microstructure influence. The results show that: MgCO3 and SiC AZ63 magnesium alloys of organizatio