纳米氧化锌的表面改性.pdf

13 2 Vol. 13, o. 2 2004 6 M I I G MET ALLURGY June 2004 : 1005- 7854(2004) 02- 0050- 03 1,2 2 2 2 2 2 3 马正先 , 韩跃新 , 印万忠, 王泽红,袁致涛 , 于富家 , 马云东 ( 11 济南大学, 济南250022; 21 东北大学, 沈阳110004; 31 辽宁工程技术大学, 阜新123000) : , , , , , , , T EMIR , , : 40%, 30min : ; ; ; : TB383 : A SURFACE MODIFICATIO OF A OMETER-SIZED ZI C OXIDE 1, 2 2 2 2 MA Zheng-x ian , HA N Yue-x in , YIN Wan-z hong , WA N G Ze-hong , 2 2 3 Y UA N Zhi-tao , Y U Fu-j ia , MA Yun-dong ( 11Jinan Universit , Jinan 250022, China; 2. Northeaster n Universit , Sheng ang 110004, China; 31L iaoning Technical Universit , Fux in 123000, China) ABSTRACT: In application of newly prepared nano-sized zinc oxide,it is directly added into organic compound mostly,which is difficult comparatively.So, it is indispensable that surfacemodification of nano-sized zincoxide is done. The tests on surface modification of self-made nano-sized zinc oxide were carried out with titanate as cou- pling agent.Results indicate that the use level of coupling agent is the most important factor to influence the modification and its dosage is well over that needed for common powder.By means of IR and TEM,unmodified and modified nano-sized zincoxides are investigated and theoptimal modifying conditions arethe agent dosageof 40% and modifying time of about 30min. KEY WORDS: ano-sized zincoxide; Surface modification; IR-spectrum; T itanate coupling agent 1 引 言 ,