间接碘量法测定铜合金中的铜（Indirect iodine method is used to determine copper in copper alloys）.docVIP

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间接碘量法测定铜合金中的铜（Indirect iodine method is used to determine copper in copper alloys）.doc

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间接碘量法测定铜合金中的铜（Indirect iodine method is used to determine copper in copper alloys）

间接碘量法测定铜合金中的铜（Indirect iodine method is used to determine copper in copper alloys） Experimental questions answered 1. How can the Na2S2O3 solution be prepared to dissolve the Na2S2O3 in distilled water before boiling A: Na2S2O3 is not a benchmark, so you cant make the standard solution directly Its easy to break down, because the microbes in the water, the CO2, the O2 in the air, react In addition, trace Cu2 + or Fe3 + in water can also promote the decomposition of Na2S2O3 solution. 2. Why did you want to add KI when the concentration of potassium dichromate to the Na2S2O3 concentration? Why would you want to dilute the starch before it was placed in the dark for 5 minutes Answer: (1) the role of KI has two points: one is to quantify the I2 with the action of the K2Cr2O7, to calibrate Na2S2O3. The second is I2 complexing I3 - contact ion to prevent the volatilization of I2. (2) when the K2Cr2O7 and KI are used, 5 minutes are placed in the dark place because of the protection of the light from the i-by air oxidation and the function of K2Cr2O7 and KI. Therefore, the solution should be applied Store in iodine flask or conical flask (cover the surface of the container), put some time in the dark, and after the reaction is complete, titration will be made. (3) to maintain the acidity of 0.2-0.4 mol · l-1 to keep the calibration, dilute the solution before titration. (4) due to the partially oxidized starch in I2, it is not obvious that the endpoint is early and not obvious, so the starch indicator will not be added until the end of the indirect iodization method, i.e. the I2 is the most By titration, when the solution is light yellow, starch is added. 3. When measuring the copper, why does the pH have to maintain a low or high effect between 3.5 and 4 A: the method used to determine copper is indirect iodine, which must be carried out in neutral or weak acidic solution. The following reactions will occur in the alkaline solution: I2 and S2O32 - S2O32 - + 4I2 = 2 SO42 -