毕业论文：氧化铋氧化钛纳米管复合材料的制备与表征.doc

Bi2O3 / TiO2纳米管复合材料的制备与表征 毕业设计（论文） 题 目：Bi2O3/TiO2纳米管复合材料的制备与表征 Bi2O3/ TiO2纳米管复合材料的制备与表征 摘要 纳米二氧化钛是一种性能优异，广泛用于环境保护的光催化剂，但由于其带隙较宽（3.2eV），只能被波长较短的紫外线激发，故对太阳能的利用率较低；而且，由于光生电子与空穴的复合，导致其光量子效率降低。半导体复合是克服上述不足的一种良好纳米二氧化钛改性方法。 本论文以二氧化钛粉体为前驱体，以10mol/L的NaOH溶液为强碱介质，采用水热法合成二氧化钛纳米管。采用XRD、TEM对样品进行表征，初步分析了二氧化钛纳米管的形成过程及机理。采用化学沉积-锻烧法制备了Bi2O3/TiO2纳米管复合材料，并用XRD、TEM、UV-vis、荧光光谱对其物相、形貌、光谱特性进行表征。实验结果表明，随着Bi2O3负载量的增加，TiO2纳米管中金红石相含量增多。当Bi2O3含量为3.0%时，可以获得牢固附着在TiO2纳米管表面，粒径约3nm，高度分散的Bi2O3纳米粒子。Bi2O3抑制了TiO2纳米管光生电子和空穴的复合，降低了TiO2纳米管的荧光强度。UV-vis分析结果表明，负载1%的Bi2O3后，TiO2纳米管的吸收峰从380nm移至400nm，增强了TiO2纳米管对可见光的吸收。 关键词：TiO2纳米管 ；复合半导体；光电效应；光催化性能 Preparation and characterization of synthesis of bismuth dioxide - titanium dioxide nanotube composites ABSTRACT Titanium dioxide is an excellent photocatalyst which has widely used in environmental protection. However, it can only be excited by ultraviolet due to its wide band-gap (3.2 eV). And the high recombination rate of photogenerated electron/hole pairs of TiO2 results in lower light quantum efficiency. Combination with other semiconductor on titanium dioxide is a good method to overcome those shortcomings mentioned above. In the present thesis, TiO2 nanotubes were prepared via a hydrothermal approach using TiO2 powder as raw materials and 10 M NaOH solution as alkaline medium. XRD and TEM were applied to characterize TiO2 nanotubes. The formation mechanism of TiO2 nanotubes was discussed. A chemical deposition-calcination approach was proposed to fabricate Bi2O3/TiO2-NTs composites with TiO2-NTs prepared via a hydrothermal method as substrates. The samples were characterized by XRD, TEM, PL, and UV-vis. It was found that Bi2O3 nanoparticles with sizes of 3nm were highly and tightly dispersed on the surface of TiO2-NTs when the content of Bi was 3.0 at. %. Combination of Bi2O3 could effectively prohibit the recombination photogenerated electron/hole pairs. The absorption edge of TiO2-NTs shifts from 380 nm to 400 nm when 1.0 at. % Bi