硫脲在碱性介质中的电化学行为 - 中国有色金属学报.pdfVIP

第 18 卷第 4 期 中国有色金属学报 2008 年 4 月 Vol.18 No.4 The Chinese Journal of Nonferrous Metals Apr. 2008 文章编号：1004-0609(2008)04-0733-05 硫脲在碱性介质中的电化学行为 王云燕，柴立元 ( 中南大学 冶金科学与工程学院，长沙 410083) 摘 要：为表征硫脲在碱性介质中的电化学行为并为碱性硫脲浸金提供理论依据，采用稳态极化法和循环伏安法 等电化学测试技术，系统研究碱性介质中硫脲的氧化分解电势、硫脲分解与浓度的关系。结果表明：硫脲的阳极 氧化分解为不可逆反应，其氧化分解峰电流对应的电势约为 0.5 V 。硫脲浓度由0.05 mol/L 增加至 0.15 mol/L，其 −4 −4 氧化分解的峰电流由 1.559×10 A 增大至 9.068×10 A ，峰电势由 0.505 V 负移至 0.430 V，硫脲分解加剧。随pH 值的升高，硫脲的氧化分解趋于严重，碱性介质中硫脲易于分解。 关键词：硫脲；碱性介质；分解；电化学行为 中图分类号：TF 801 文献标识码：A Electrochemical behaviors of thiourea in alkaline medium WANG Yun-yan, CHAI Li-yuan (School of Metallurgical Science and Engineering, Central South University, Changsha 410083, China) Abstract: In order to describe electrochemical behaviors of thiourea and provide fundamental for gold ore leached by alkaline thiourea system, the decomposed potential of thiourea oxidized in alkaline medium and the relationship between decomposition and concentration of thiourea were studied in detail by the methods of electrochemical techniques, such as stable polarization and cyclic voltammetry. The results indicate that the decomposition of thiourea is irreversible, and the corresponding decomposition potential is 0.5 V. With the addition of thiourea concentration from 0.05 mol/L up to 0.15 mol/L, the decomposition of thiourea is accelerated, the peak current increases from 1.559×10−4 A up to 9.068×10−4 A and the peak potential moves from 0.505 V down to 0.430 V. The decomposition of thiourea becomes serious with