钝化剂对猪粪厌氧发酵产气特性及重金属含量的影响.doc

钝化剂对猪粪厌氧发酵产气特性及重金属含量的影响 张辉，刘艳杰，林天驰，陈梅，马群，张镇，李轶( （沈阳农业大学 工程学院，辽宁 沈阳 110866） 摘 要：为了减少重金属污染，本文在猪粪厌氧发酵过程中添加钝化剂，探讨钝化剂对甲烷含量、重金属含量的影响，以期为减少重金属污染提供有效途径。本文选用钝化剂种类、钝化剂浓度及温度三个因素，每个因素取三个水平，采用正交设计的方法，对猪粪进行厌氧发酵。结果表明：影响猪粪厌氧发酵甲烷含量的因素主次顺序为：钝化剂种类、温度、钝化剂浓度,甲烷含量最高的处理为采用7.5％浓度的活性炭钝化剂，在35℃条件下反应的处理组合；影响猪粪厌氧发酵后重金属Cu含量的因素主次顺为：温度、钝化剂种类、钝化剂浓度， Cu含量减少最多的处理为温度为25℃，5％浓度粉煤灰钝化剂的处理组合；影响猪粪厌氧发酵后重金属Zn含量的因素主次顺为钝化剂种类、温度、钝化剂浓度, Zn含量减少最多的处理为：5％浓度的粉煤灰钝化剂，温度为25℃的处理组合。猪粪厌氧发酵后，各组试验中沼渣中重金属含量均降低,沼液中重金属含量均增加，大多数组重金属总的含量减小。 关键词：钝化剂；猪粪；厌氧发酵；重金属甲烷含量 中图分类号： 文献标识码：A 文章编号： Effects of adding passivator on pig manure anaerobic fermentation biogas production and the content of heavy metal ( Engineering College, Shenyang Agricultural University, Shenyang 110866, China) Abstract: In order to reduce the heavy metal pollution, in this article ,the passivation agent is added in the pig anaerobic fermentation process, exploring the passivator’s influence on anaerobic fermentation gas, methane content, the heavy metal content .So that we can provide an effective way to reduce the pollution of heavy metals. This article selects three factors: the passivation agent type, the passivation agent concentration and the temperature, each factor in three levels. The pig manure was taken as anaerobic fermentation with the method of orthogonal design.The results show that: The primary and secondary order of three factors’ influence on pig anaerobic fermentation methane content is : the passivation agent type, the temperature, the concentration of passivator;The best treatment group is : 7.5% activated carbon at 35℃; The primary and secondary order of three factors’ influence on pig anaerobic fermentation Cu content is: the temperature, the passivation agent type and the concentration of passivator. The Cu conten decling biggestly when the pig anaerobic fermentation adding 5% concentration of coal ash passivation agent at 25℃; The primary and secondary order of three factors’ influence on pig anaerobic fermentation Zn