微胶囊复合相变材料的制备及性能表征 周建伟.pdfVIP

37 6 　　　 Vo.l37 No.6 2008 6 AppliedChemicalIndustry Jun.2008 1 2 1 1 周建伟,黄建新 ,柳少军, 陈焕芝 (1. , 　453000;2., 　453000) 　:, , 。 、、、 。 , , 160 ℃, 15.3 ℃, 132.3 J/g。, 20 μm, 0.5 mL/min , / 1 ∶1.5, 。 :;;; :O631.5　　　:A　　　:167 1-3206 (2008)06-0630-03 Preparationandcharacterizationofmicrocapsule forcompositephasechangematerial 1 2 1 1 ZHOUJian-wei, HUANGJian-xin, LIUShao-jun, CHNHuan-zhi (1.SchoolofChemicaland nvironmentalngineering, XinxiangColleg,eXinxiang4 53000, China; 2.DeparmtentofApplicationsBiology, XinxiangUniversity, Xinxiang4 53000, China) Abstrac:tAmicroencapsulatedphasechangematerialwaspreparedbythein-situpolymerizationmethod usinglowmeltingpointPCM, melamine-urea-formaldehydeprepolymerascorematerialandshellmaterial respectively.Theshellstructur,eappearancecharacterandthethermalpropertiesofthemicrocapsulewere investigatedbyFT-IR, SM, DSCandTG.Theexpermientalresultsshowedthatthecompositephase changematerialcanwithstandahightemperatureupto160 ℃, andthemeltpointandenthalpywere 15.3 ℃ and132.3 J/g, respectively, theaveragediameterofthemicrocapsuleissmallerthan20 μm, and theparticlesizeiscentralizedwhenthedroppingrateofthesolidifyingsolventislessthan0.5 mL/min. Theenergycapacitydependedthecore-to-coatingrati,oandtheoptmiizedcore/coatingratiowas1 ∶1.5. Thehydrophilicityofthemicroencapsulatedphasechangematerialreducedwithincreasingcontentofcore inthePCM. Keywords:microcapsul;ephasechangemateria1;thermalenergystorag;ein-situpolymerization [1-5] 　　 20 。, 70 ,