微胶囊相变材料的制备与特性研究 鄢瑛.pdfVIP

微胶囊 变材料的制备与特性研究/鄢　瑛等 ·49 · 鄢　瑛, 张会平, 刘　剑 (, 5 10640) 　　采用原位聚合法制备以石蜡为芯材、脲醛树脂为壳材的微胶囊 变材料, 并通过丝网印刷技术, 结合热 固性聚氨酯网印粘合剂将微胶囊涂布于棉布上。考察了乳化剂的种类及用量和人工汗液对微胶囊性能的影响, 分析 了对经MCPCM 涂布的棉布布料的热性能。研究结果表明,使用复合乳化剂制备的微胶囊 变材料表面光滑, 密封 良好。微胶囊 变温度和 变潜热分别为34.10 ℃和143.8J/g, 经过 20 次热循环后, 变温度和 变潜热都变化不 大。微胶囊经人工汗液分别浸渍20min、40min 和60min 后, 其 变温度和 变潜热无明显变化。微胶囊与网印粘合 剂结合的复合材料涂布于棉布上, 其 变温度和 变潜热均有降低。 　　　　 Preparation and Characteristics of Microencapsulated Phase Change Materials YAN Ying, ZHANG Huiping, LIU Jian (Sch l f Chemistry and Chemical Engineering, S uth China University f T echn l gy, Guangzh u 510640) Abstract　　The micr encapsulated phase change material is prepared by in-situ p lymerizati n w ith urea-f rmal- dehyde resin as shell and paraffin as c re, and the c tt n cl th c ated with micr capsules by screen printing is als pre- pared.The effects f c mp und emulsifier and artificial sweat n the pr perties f micr capsules are analyzed.And the thermal pr perties f the c tt n cl th c ated with the micr capsules are als tested.The result sh w s that the surface f micr capsules prepared by the c mp und emulsifier is sm th and sealed w ell.The phase change temperature and the latent heat st rage capacity are 34.10 ℃and 143.8J/g, respectively.After heating-c ling recy cle f r 20 times, there is n significant dif ference in the phase change temperature and the latent heat st rage capacity.The thermal pr perties f the micr capsules which are dipped in the artificial sweat f r 20min, 40min and 60min are nearly the same as bef re.The phase change temperature and the latent heat st rage capacity f the c mplex materials c mp sed f mi- cr capsules and the adhesive which are c ated n the c tt n cl th b th decrease a little.