微纳米水合盐相变材料Na 2SO 省略 4 10H 2O的仿生合成与表征 黄保军.pdfVIP

Vol.39 No.1 　　　　　 39 1 ·52 · NEW CH EM ICA L MAT ERIA LS 2011 1 Na2SO4 ·10H2O 1 2 1 1 ＊ 黄保军 　何　琴 　杨风岭 　郑　直 (1.许昌学院表面微纳米材料研究所,许昌461000;2.许昌学院化学化工学院, 许昌461000) 　　以定量滤纸 生物模板成功制备了具有滤纸形貌的微纳米Na SO 晶体, 经过吸水和低温的结晶过程合成 2 4 了相变材料Na SO ·10H O。并借助扫描电子显微镜(SEM )、X-射线粉末衍射仪(XRD)和差示扫描量热仪(DSC)对产 2 4 2 物进行了表征。结果表明, 产物纯度很高, 且很好地遗传了模板的形貌。 同时, 最终合成的相变材料Na SO ·10H O 表 2 4 2 现出了良好的储能效果, 相变潜热大于 200J/ 。 　相变材料, 十水合硫酸钠, 仿生合成 Biomimetic synthesis and characterization of Na2SO4 ·10H2O as phase change materials with micro/nano structure 1 2 1 1 Huan Baojun 　He Qin 　Yan Fen lin 　Zhen Zhi (1.Institute of Surface Micro and Nano M aterials , Xuchan 461000; 2.Colle e of Chemistry and Chemical En ineerin , Xuchan University, Xuchan 46 1000) The biomorphic Na SO cry stal were prepared usin filter paper as bio-templates, and transformed it into Abstract　 2 4 Na SO ·10H O durin the process both drinkin and cry stallization under low temperature.Finally, S EM, XRD and 2 4 2 DSC were used to characterize the morpholo y, cry stalline phase and thermal property of the products.The results show ed that products had hi h purity and mimicked well morpholo ies of the filter paper.At the same time, the resulted phase chan e materials of Na SO ·10H O showed ood heat stora e property and their phase chan e latent hea