锂离子正极材料LiNi0.DOC

锂离子正极材料LiNi0.5Mn0.3Co0.2O2的合成与掺杂Al的性能研究 钟盛文 钟风娣 张骞 (江西理工大学材料学院，江西 赣州 341000) 摘要：采用共沉淀法合成镍钴锰氢氧化物前躯体，使其和碳酸锂混合均匀后高温焙烧合成锂离子正极材料LiNi0.5Mn0.3Co0.2O2，并研究了掺杂Al(OH)3对材料循环性能的影响。用X-射线衍射和扫描电镜对合成的粉末进行了表征，用电性能测试仪研究了材料的电化学性能。研究发现：在850℃焙烧的材料具有最优的电性能，1C电流初始放电比容量达到157.2mAh/g(2.75-4.2V)，循环50次放电比容量保持率为94.8%，循环100次材料的放电比容量保持率为90.1%。通过少量掺杂Al(OH)3的电池材料结晶性有所提高，晶型趋于完整，但是材料的放电比容量有所降低，前100次循环掺杂对材料循环稳定性的无显著改善效果。 关键词：锂离子电池正极材料；LiNi0.5Mn0.3Co0.2O2； Al掺杂；共沉淀法 Synthesis and properties of LiNi0.5Mn0.3Co0.2O2 and Al-doped as a cathode material for lithium-ion battery ZHONG Sheng-wen ZHONG Feng-di ZHANG Qian (Faculty of Material, Jiangxi University of Science and Technology, Ganzhou 341000,China) Abstract：The cathode materials LiNi0.5Mn0.3Co0.2O2 were synthesized though high temperature calcinate the compound of lithium carbonate and cobalt nickel manganese hydroxide precursor, which prepared by liquid co-precipitation technique， and Al(OH)3 doped material’s cycle performance was studied. The prepared powders were characterized by powder X-ray diffraction, scanning electron microscope, and charge/discharge. The material calcinated at 850℃ showed the best performance, the first discharge capacity of 2.75-4.2V and at 1 C was 157.2 mAh/g, the capacity retention ratio was 94.8% after 50 cycles and 90.1% after 100 cycles. Through a small amount of Al dopimg, the material’s crystalline was improved and the crystal type tended to complete, but the discharge capacity reduced, while it didn’t have obvious influence on the material’s cycle stability at the former 100 cycles.Keywords: lithium-ion battery cathode materials; LiNi0.5Mn0.3Co0.2O2; Al doping; co-precipitation method 锂离子电池在日常生活中随处可见，但其使用过程中出现了较多的问题，比如容量衰减快、稳定性不好、安全性能不佳等。锂离子电池正极材料性能的好坏直接决定了电池的使用性能，如何改善锂离子正极材料的使用性能一直是广大研究者不懈努力研究的方向。正极材料的合成主要有化学共沉淀法[1]、固相反应法[2]、溶胶-凝胶法[3][4]、喷雾热解法LiNixMnyCo1-x-yO2，其有一种协同效应，材料具有较高的放电比容量、成本较低、而正极材料LiNi1x-yCoxMnyO2的掺杂改性化合物稳定性能好、安全性高LiNi1/3Co1/3Mn1/3O2，并研究了掺杂Al、Fe 合成LiNi1/3Co1/3-xMxMn1/3O2 (M=Fe和Al)，发现少量的Al(x1/20)掺杂可以提