六边形二氧化硅的热稳定和小孔消除.pdf

Microporous and Mesoporous Materials 190 (2014) 227–233 Contents lists available at ScienceDirect Microporous and Mesoporous Materials journal homepage: www.elsevi /locate/micromeso About the thermal stability and pore elimination in the ordered hexagonal mesoporous silica SBA-15 T. da Silveira, C.M. Awano, D.A. Donatti, F.S. de Vicente, D.R. Vollet ⇑ UNESP, Univ Estadual Paulista, IGCE, Campus de Rio Claro, Brazil a r t i c l e i n f o a b s t r a c t Article history: Ordered hexagonal mesoporous silica was prepared using Pluronic P123 template and removal of the Received 8 July 2013 polymer by washing in ethanol. The thermal stability and the pore elimination was studied under heat Received in revised form 6 February 2014 treatment by a fixed time at 500, 600, 750, 825, 900, and 1050 C. The most part of the porosity is built Accepted 11 February 2014 up by cylindrical pores belonging to the ordered hexagonal 2D pore structure. The lattice parameter and Available online 18 February 2014 the pore volume of the hexagonal 2D structure diminish regularly with the temperature up to 900 C. All porosity is eliminated at 1050 C. The porosity elimination occurs in a mechanism described by a geomet- Keywords: ric model of contracting area, in which the diameter of the cylindrical pore diminishes while its length is Ordered mesoporous silica kept constant. An act