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纤维素讲解(Cellulose explanation)
纤维素讲解(Cellulose explanation)
Cellulose group summary
Crew: Liu Miao Zhang Liu Chen Mingsong Wen Siyang Sun Xiaobo Yu Kun
Text part:
Degradation of cellulose: the development of efficient and green solvent for natural cellulose has been one of the focuses of research. First of all, the room temperature ionic liquid in the volatile, stable property, strong polar advantages in many areas is considered as green solvent instead of conventional organic solvent; and as cellulose solvent, dissolving cellulose without activation, ionic liquids are easy to recycle and open up a new path for the development and utilization of the natural fiber prime. Ionic liquid as the direct solvent for cellulose, dissolution process is considered a physical process completely, with no occurrence of any chemical reaction. But the actual situation is cellulose in solution, must be accompanied by chain breaks, or degradation; regenerated cellulose materials mechanical properties, thermal stability and molecular therefore, the value of the effective control of thermal degradation has become an important issue in the process of cellulose. The research direction in the literature is the wood pulp and cotton pulp as raw material, using ionic liquid as a solvent and degradation experiment of mixed heating at a certain temperature and time, in order to get the data and the degree of polymerization of native wood, cotton pulp were compared, get a degree and amplitude of the degradation, and discusses its the degradation mechanism of cellulose degradation. And obtained a series of rules: under normal temperature, the cellulose ionic liquid solution, placed 2 and a half months is not degraded, this being conducive to industrial production of cellulose; at a higher temperature, cellulose dissolving time is longer, the greater the magnitude of degradation; but at the same time and temperature, the degradation of cotton pulp wood pulp was higher; cellulose ionic liquid solution at the same time, the highe
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