四叔丁基萘酞菁铅化合物的非线性和光限幅特性.pdfVIP

2008年第66卷 化 学 学 报 VOl_66．20o8 第5期，563~566 ACTA CHIMICA SINICA No．5．563～566 · 研究论文· 四叔丁基萘酞菁铅化合物的非线性和光限幅特性 刘大军木 何兴权 高正国 段 潜 周奋国 f长春理工大学化学与环境工程学院 长春 130022) 摘要 合成了四叔丁基萘酞菁铅【(卜Bu)4NcPb】化合物．利用元素分析、红外光谱、核磁共振氢谱等方法，验证了化合物 的分子结构．应用调Q倍频ns／ps Nd：YAG脉冲激光系统，在波长为532 nm下，研究了化合物的非线性和光限幅特性． 测得化合物的非线性折射率n2和三阶非线性极化率 分别为2．42X 10 和7．91×10 esu，通过计算得到分子极化 率y’为3．4X 10—29 esu．在透过率69％时限幅阈值为1522 mJ／cm2，箝位值为553 mJ／cm2，有效激发态与基态吸收截面比 为3．16． 关键词 非线性光学；Z-扫描；萘酞菁 Nonlinear and Optical Limiting Properties of Tetra tert-ButyInaphthaIOCyanine Lead LIU，Da—Jun HE，Xing—Quan GAO，Zheng—Guo DUAN，Qian ZHOU，Fen—Guo (College ofChemical and Environmental Engineering，Changchun University ol’Science and Technology，Changchun 130022) Abstract The compound of tetra tert-butylnaphthalocyanine lead was synthesized．Th e structure of the compound was characterized by means of elemental analysis，infrared spectrum and hydrogen nuclear mag— netic resonance spectrum．A frequency—doubled Q switched Nd：YAG pulse laser system with ns／ps laser pulse was used for studying the nonlinear and optical limiting properties of the synthesized compound at the wavelength of 532 nin．Th e nonlinear refracting index，n2，and third-order nonlinear polarizability， were determined to be 2．54~1 0一¨and 9． 5 1×1 0一 esu．respectively．The molecular polarizability of the com— pound y’was calculated to be 3．3×10一 esu．When visible light transmittance was 69％，the limiting thresh— old value was 1 522 mJ／cm ，the clamp value was 553 rnJ／cm ，and the ratio of absorption sectional area of effective excited state to that of ground state was 3．16． Keywords nonlinear optics；Z