高压顶空毛细管气相色谱法测定聚合物乳液中的残余单体-环境科学.PDF

19987 ENVIRONMENTAL SCIENCE Jul. ,1998 * 林来军 佟柏龄 (, 101149) (,100037) 徐维并 (,100085) 5. ,., 3 4 ,10 10 , 5 , 1 / . RSD g g ,,,. Determination of Residual Monomers in Emulsion by High Pressure Sampling Accessory Headspace Capillary Gas Chromatography Lin Laijun Tong Bailing (Beijing Eastern Rohm Haas Co.LTD. 101149) (Institute of Rock Mineral Analysis,CAGS 100037) Xu Weibing ( - , , 100085) Research Center for Eco Environmental Sciences Chinese Academy of Sciences Beijing Abstract5Residual monomers were detected successfuly by using high pressure sampling ac- cessory in headspace Predisposal for samples is not necessary It was showed that the linear. . 3 4 range is 10 10 ,the relativestandard deviationis lower than 5 (n= 8)and the relativecoeffi- cients are 0.9906,0. 9995,0.9987,0.9996and 0.9961for VAC,EA,MMA,BA and ST respec- tively.The detection limit is less than 1g/g. , , , . Keywords polymer emulsion residual monomer headspace high pressure sampling accessory , HS40/ ; 1022 [ 1] [2] , ;OKIDATA-320. [3] , : (VAC) , 2, ( EA), (MMA), ( ) ( - ), ( ), 50g/g . BA N BAC ST ,. 5, .2 , SH40:120, , , 160,180,