茶多酚纳米银的制备及其对直接蓝15的催化降解性能.DOC

研究与技术 茶多酚纳米银的制备及其对直接蓝15的催化降解性能 张俊，姚平，许磊，陶然 (苏州经贸职业技术学院 纺织服装与艺术传媒学院，苏州 江苏 215009) 摘要：利用茶多酚作为还原剂和稳定剂来制备纳米银，所得茶多酚纳米银溶液在紫外-可见吸收光谱430 nm处存在明显的吸收峰，经激光粒径仪分析所得茶多酚纳米银粒子的平均直径为68.42 nm。为了探究茶多酚纳米银粒子的催化性能，文章使用茶多酚纳米银和还原剂硼氢化钠对直接蓝15进行催化降解，经过80 min的反应后，直接蓝15的降解率在添加纳米银的条件下达到91%；而如果溶液中不添加纳米银粒子，相同时间后直接蓝15的降解率只有35%。经过还原降解后，直接蓝15大分子结构中的偶氮基发生断裂，从而破坏了染料的发色体系。 关键词：茶多酚纳米银；生物法制备；催化性能；直接蓝15；还原降解 中图分类号：TS190.2 文献标志码：A 文章编号：1001-7003(2017)00-0000-00 引用页码： 收稿日期：2016-11-06；修回日期：2017-00-00 基金项目：江苏省科技厅自然科学基金项目(B；江苏省高校自然科学研究面上项目(16KJB610018)；中国纺织工业联合会科技指导性项目(2015060)；苏州经贸职业技术学院院级科研项目(KY-ZR1612) 作者简介：张俊(1979)，男，副教授工学博士，主要从事功能性纳米材料的开发与研究。 Biogenic synthesis of silver nanoparticles tea polyphenols and catalytic performance for reductive degradation of Direct Blue 15 thereof ZHANG Jun, YAO Ping, XU Lei, TAO Ran (Suzhou Institute of Trade and Commerce, School of Textile Clothing and Arts and Media, Suzhou 215009, China) Abstract: The tea polyphenols silver nanoparticles prepared with tea polyphenols as reducing and capping agent shows an obvious absorption peak at 430 nm in the UV-vis absorption spectrum. The average diameter of AgNPs in the solution was detected to be around 68.42 nm with optical particle size analyzer. In order to study the catalytic performance of AgNPs, catalytic degradation of Direct Blue 15 was performed by using AgNPs and NaBH4 (reducing agent), and it was found that the degradation rate of Direct Blue 15 reached up to 91% after 80min reaction if silver nanoparticles were added, while the degradation rate was only 35% if no silver nanoparticle was added under the same conditions. The azo groups in the macromolecular structure of Direct Blue 15 were broken after reductive degradation, which destroyed the chromophoric system of dye. Key words: tea polyphenols AgNPs; biogenic synthesis; catalytic performance; Direct Blue 15; reductive degradation 染料废水具有色度深、污染物浓度高、生物难降解、含有毒及致癌物质等特点，如果处理不当，易引发很多环境问题[1]。而目前处理染料废水的主要方法有生物法、物理法及化学法[2-4]，但无法达到理想的处理效果，使得印染废水处理成为工业废