顶坛花椒和四川茂县大红袍花椒挥发油的GC-MS分析比较.pdfVIP

安徽农业科学,Journal of Anhui Agri .Sci .2009 ,37(5) :1879 - 1880 , 1885 责任编辑 罗芸 责任校对 张士敏 顶坛花椒和四川茂县大红袍花椒挥发油的GC- MS 分析比较 1,2 3 陈训 ,贺瑞坤 ( 1. 中南林业科技大学, 湖南长沙410004 ;2 . 贵州科学院, 贵州贵阳550001;3 . 广东省华南植物园, 广东广州510520 ) 摘要 [ 目的] 分析顶坛花椒挥发油的含量和化学组成 。[ 方法] 利用气相 色谱- 质谱 法( GC- MS) 对贵州顶坛花椒和四 川省茂县大红袍 花椒 的挥发油化学成分进行 了分离鉴定, 用峰面积 归一法测定 了已确 定组分的相对含量, 并对2 种花椒 的挥发油化学成分进 行比较 。 [ 结果] 贵州顶坛花椒共 鉴 定 出29 个 化合 物, 按 峰面积 计算, 检 出率 为99 .417 % , 四 川省 茂 县大红袍 鉴定 出38 个 化合 物, 检 出率 为 97 .685 % ; 顶坛花椒挥发性成分 中的芳樟醇含量尤其高, 达到茂县大红袍 的4 .56 倍 。顶坛花椒挥发油中单 萜和倍半 萜衍生物含 量 高达 93 .985 % , 而茂县大红袍只有77 .256 % 。感官评价表 明, 顶坛花椒 的香味比茂县大红袍 浓郁 。[ 结论] 顶坛花椒 与茂县大红袍 的挥发油均 有多种成分和含量存在显著差异。 关键词 顶坛花椒; 茂县大红袍花椒; 挥发油; 气相 色谱- 质谱 中图分类号 S636 .9 文献标识码 A 文章编号 0517 - 6611(2009) 05 - 01879 - 02 Analysis and Comparison on Volatile Oil of Zanthoxyl u m pl ani spinu m var . di nt anensi s and Zant hoxyl u m bungeanu m Dahongpao in Maoxian County of Sichuan Province by GC- MS CHEN Xun et al ( Central South University of Forestry and Technology , Changsha , Hunan 4 10004) Abstract [ Obj ective] The purpose was to analyze the content and chemical co mposition of volatile oil of Zanthoxylu m pl anispinu m var . di nt anensi s . [ Method] The chemical ingredients of volatile oil in Z . P . dint anensis of Guizhou and Zant hoxylu mbungeanu m Dahongpao in Maoxian County of Sichuan Province were isolated and identified by utilizing GC- MS , the relative contents of confir med components were deter mined with peak area nor malization method , and the chemical ingredients of volatile oil of two kinds of Z . bungeanu m was compared . [ Result ] There were 29 compounds identified from Guizhou Z . P . dint anensis with detection rate of 99 .417 % in light of counti ng of peak area ; 38 co mpounds were identified from “Dahongpao”Z .