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离子共存(Ion coexistence)
1. colorless transparent conditional type
If the title is limited, is not colorless solution containing nonferrous ions, namely Fe2+ (light green), Fe3+ (brown), Cu2+ (blue), MnO4 (purple) plasma. If transparent, the solution does not form cloudy or precipitate (irrespective of the color of the solution). Such as Ag+ and Cl -, Br, I, Ca2+, and SO42 -; CO32 SO32; Ba2+ and CO32, SO32, etc. the reaction of SO42 - in aqueous solution, precipitation to produce turbid or obvious, they cannot coexist a lot.
Example 1.. In a colorless transparent solution, the following groups of ions can coexist in large numbers
A.H+, Cl -, Ba2+, CO32
B.Ag+, I, K+, transport are No3
C.K+, oh -, Cl -, Na+
D.Fe3+, Cl -, transport are No3, Na+
Analysis: the correct option should meet two conditions: colorless, transparent and able to coexist in a large amount. The answer is C.
2. acid condition type
A common description of acid solution, PH=1 solution, PH can make the litmus red solution, purple litmus solution red solution, methyl orange red solution, adding magnesium powder can release hydrogen solution, C (OH -) =1 * 1014mol L-1 solution.
If the title is defined in acidic solution, the solution in the presence of H+, which does not contain large amounts of OH and weak acid ion (such as CO32, SO32, S2, F, ClO, CH3COO, C6H5O, PO43, AlO2, SiO32 etc.) and weak acid type root ion (such as HCO3, HSO3, HS, HPO42, H2PO4 etc.).
In 2. cases (2005 national college entrance examination questions? Henan province volume) in the solution of pH=1, can be a large number of coexisting ions are ()
A.K+, Na+, SO42 -, S2O32
B.NH4+, Mg2+, SO42 -, Cl -
C.Na+, K+, HCO3, Cl
D.K+, Na+, AlO2 and transport are No3
Analysis: the correct option should satisfy pH=1 (with H+ presence) and can coexist in two conditions. The answer is B.
3. alkaline conditioned type
A common description of alkaline solution, PH=14 solution, PH can make the litmus blue solution, red litmus blue solution and phenolphtha
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