超声促进浸渍法制备WO3ZrO2固体超强酸催化剂.pdfVIP

4 1 6 四川大 学 学 报 (工程 科 学版 ) Vo.l4 1 No.6 2009 11 JOURNALOFSICHUANUNIVERSITY(ENGINEERINGSCIENCEEDITION) Nov.2009 　　:1009-30 87 (2009 )06-0084 -05 WO/ZrO 3 2 1 2 2 1 张　存 马春艳 刘晓勤 (1. 2 10009;2. 225002) 　: Zr(OH) WO/ZrO 4 3 2 BET、XRD、NH-TPD SEM。 3 ZrO(t) 2 。 。 :;;;; :0 64 3 :A PreparationofWO/ZrO SolidSuperacidCatalysts 3 2 byUltrasonicImpregnation 1 2 2 1 ZHANGCun MAChun-yan LIUXiao-qin (1.CollegeofChem.andChemicalEng. NanjingUniv.ofTechnolNanjing2 10009 Chin;a 2.CollegeofChem.andChemicalEng. YangzhouUniv. Yangzhou225002 China) Abstrac:tWO/ZrO solidsuperacidcatalystswerepreparedbyusingZr(OH)assupporterwithultrasonicmi- 3 2 4 pregnationandgeneralmipregantionrespectively.ThecatalystswerecharacterizedbymeansofBET XRD NH 3 -TPDandSEM.Theresultsrevealedthatthecatalystpreparedwithultrasonicmipregnation compardwithgener- almipregantionpossessedlargesurfaceareasandsupportedmoredispersiontungsteactivecomponen.tCalcinedat hightemperatureZrO inthecatalystyetexistedmainlyinthetetragonalphaseandthecatalystpresentedhighera- 2 cidicstrengthandacidamount.sFurthermorethecatalystwasdispersedinsmallparticleandgavestrongcata