PAN基凝胶聚合物电解质超级电容器的研究.pdf

33 11 V o.l 33, . 11 2006 11 A pp lied Science and T echno logy N ov. 2006 : 1009- 671X ( 2006 11- 0061- 05 PAN , , ( , 15000 1 : PAN PAN . . , . , PAN 7. 54 m s cm- 1, , PAN 2. 5 2 2 V, 8. 92- 12. 6 cm , 20. 6 F / g( i= 0. 5 mA / cm . : ; ; ; : TM 912. 9 : A Investigations on supercapacitors using PAN-based gel polym er electrolytes M ENG X iang- l,i Y IN J in- ling, ZHANG Bao-hong ( Co lleg e of M ate rial Science and Chem ica l Eng ineer ing, H arbin Eng ineering U niversity, H arb in 150001, China Abs tract: Po lyacry lon itrile( PAN based ge l po lym er e lectrolytes( GPEs were synthesized. PAN-based ge l po lym er electro lytes supercapacitors w ere also fabricated. The behaviors of GPE s w ere m easured by A C mi pedance. The properties of PAN based GPEs capacito rsw ere studied by mi pedance spectrum, cyclic vo ltamm etry, constant current charge / discharge. Im pedance spectra w ere analysed by smi ulat ing equivalent circu it. The resu lt showed that the con- - 1 duct iv it ies o f the PAN-based gel polym er electro ly tes can be as h igh as 7. 54mS cm at am bient tem perature. W ith actived carbon e lectrodes, the w ork ing vo ltage o f the supercapac itors can be as h igh as 2. 5V. The internal resistance 2 of the capac itorsw ere ju st 8. 92- 12. 6 cm . T he specific capacitance of the supercapac itorsw ith PAN-based ge l 2 po lym er e lectrolytes w as obtained as high as