乙酸脱除天然竹纤维木质素的研究.PDFVIP

Vol.49 第49卷 No.07, Jul. 2012 2012年07月 第07期 研究与技术 乙酸脱除天然竹纤维木质素的研究 张袁松，蒋瑜春，胡福强，蔺俊强，谢吉祥 (西南大学 纺织服装学院，重庆 400715) 摘要：以慈竹为研究对象，对常压下乙酸脱除天然竹纤维中的木质素进行了探讨。以反应温度、乙酸体积分数、催化剂硫酸体积分数和 反应时间为单因子，考察这些因素对天然竹纤维木质素脱除率的影响。结果表明：影响因素从大到小依次为反应温度、催化剂硫酸体积 分数、乙酸体积分数和反应时间。正交试验结果表明，乙酸在脱除天然竹纤维木质素的过程中也脱除了部分半纤维素和纤维素。结合木 质素脱除率、半纤维脱除率和纤维素脱除率，得到了最佳工艺条件，即90 ℃，乙酸体积分数88 %，硫酸体积分数0.3 %，反应时间3 h， 在该条件下木质素的脱除率达到55.84 %。 关键词：天然竹纤维；乙酸；木质素；脱除率 中图分类号：TS102.23 文献标志码：A 文章编号：1001-7003(2012)07-0001-05 Study on removing the lignin of natural bamboo fibers by acetic acid ZHANG Yuan-song, JIANG Yu-chun, HU Fu-qiang, LIN Jun-qiang, XIE Ji-xiang (College of Textiles and Garments, Southwest University, Chongqing 400715, China) Abstract: Based on Sinocalamus affinis, this thesis conducts a study on removing lignin in natural bamboo fibers under atmosphere pressure by acetic acid. First, it studies reaction temperature, volume fraction of acetic acid, volume fraction of sulfuric acid catalyst and reaction time as single factors to find their respective impact on removing lignin of original bamboo fibers. The results show that their influence degrees rank in a decreasing order, i.e., reaction temperature, volume fraction of sulfuric acid catalyst, volume fraction of acetic acid and reaction time. Next, it does an orthogonal experiment, whose results display that some hemicelluloses and celluloses are removed when acetic acid removes lignin in natural bamboo fibers. In consideration of the removal rates of lignin, hemicellulose and cellulose, the optimal operating conditions are obtained, that is, reaction temperature is 90 ℃, the volume fracti