太赫兹介电谱与组分含量的关系分析及应用-红外技术.PDFVIP

第36 卷 第11 期 红 外 技 术 Vol.36 No.11 2014 年11 月 Infrared Technology Nov. 2014 太赫兹介电谱与组分含量的关系分析及应用 张 寒，张朝晖，赵小燕，张天尧，燕 芳，鲁亿方 （北京科技大学自动化学院仪器科学与技术系，北京 100083 ） 摘要：研究了固体有机样品的太赫兹介电谱与组分体积含量之间的关系。通过分析有效介质理论中的 CRI （Complex Refractive Index ）模型，得到样品的介电参数与组分体积含量的关系式。利用太赫兹时 域光谱技术测得室温下两种氨基酸样品在 0.5～2.7 THz 的介电性质，样品的折射率、介电系数及介电 损耗均随氨基酸体积含量增加而增大。选取氨基酸介电损耗谱特征峰位处的介电参数，根据 CRI 模型 进行拟合，得到折射率与体积含量的线性关系式，介电系数和介电损耗与体积含量的二次函数关系式。 研究结果有利于扩展太赫兹波段的定性定量分析手段，并对聚合物基复合材料制备有一定参考意义。 关键词：太赫兹介电谱；有效介质理论；氨基酸；复介电系数；体积含量 中图分类号：O436.3，O487 文献标识码：A 文章编号：1001-8891(2014)11-0873-07 Relationships between Terahertz Dielectric Spectra and Component Content and Their Applications ZHANG Han ，ZHANG Zhao-hui ，ZHAO Xiao-yan ，ZHANG Tian-yao ，YAN Fang ，LU Yi-fang (Department of Instrumentation Science, University of Science Technology Beijing, Beijing 100083, China) Abstract ：We study the relationship between terahertz dielectric spectra and the volume content of solid mixture sample components. Through the analysis of CRI （Complex Refractive Index ） model, which is an effective medium theory, the relationship between dielectric parameters and volume content of samples is obtained. Two kinds of amino acid samples are measured by terahertz time-domain spectroscopy （THz-TDS ） to obtain their dielectric properties in the range of 0.5-2.7 THz at room temperature. In this frequency band, their refractive index, dielectric coefficient and dielectric loss of samples increase with increasing volume fraction of amino acids. According to the CRI model, we obtain the linear relations between refractive index and volume fraction of glutamine and histid