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超临界水氧化法降解甲胺磷的研究-环境科学学报
20 6 Vol.20, o. 6
2000 11 ACTA SCIE TIAE CIRCUMSTA TIAE ov.,2000
: 2000 : X592, X703 : A
林春绵,袁细宁, 杨 馗 ( , 310032)
: . , ,
COD 97%. , COD
5
. : - d[ COD] / d = 869 10 exp( - 961
4 109 -038
10 / R T ) [ COD] [ O ] .
2 0
: ; ; ;
Study on degradation of methami nophos by supercritical water oxida
tion
LI Chunmian, YUA Xining,YA G Kui ( College of Biological and Environmental Engineering,Zhejiang University
of Technology, Hangzhou 310032)
Abstract : The oxidativedecomposition of methamidophos (organicphosphatepesticide) in supercriticalwater (SCW) is studied in this
paper. Theresults show that methamidophos can be decomposed effectively by supercritical water oxidation (SCWO) , and themaxi
mum of COD removal ratereachs 97% and more. TheCODremoval rateincreasewith the addition of temperature, pressure and res
idence time. Theoxidative decomposition dynamic equation of methamidophos in SCW is established as follow: - d[COD]/ d =
5 4 109 -038
869 10 exp(- 961 10 / R T ) [COD] [O ] .
2 0
Keywords:supercriticalwater oxidation; methamidophos; degradation; kinetics
1
[ 1]
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T c= 3743! P c= 221Mpa. ,
.,,
[2,3]
.,
.,
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: : 2000407
: (
: ( 1962 ) , , ( )
6 : 715
[4,5]
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