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Paper Journal of the Ceramic Society of Japan 115 [ 4 ] 259–263 (2007) iìãáåÉëÅÉåÅÉ `Ü~ê~ÅíÉêáëíáÅë çÑ qÉ ~åÇ _áaçéÉÇ dä~ëëÉë ~åÇ dä~ëë`Éê~ãáÅë Sasithorn KHONTHON, Shigeki MORIMOTO, Yusuke ARAI and Yasutake OHISHI School of Ceramic Engineering, Institute of Engineering, Suranaree University of Technology, 111, University Avenue, Muang District, Nakhon Ratchasima 30000 Thailand Department of Future-Oriented Basic Science and Materials, Toyota Technological Institute, 2–12–1, Hisakata, Tempaku-ku, Nagoya-shi, 468–8511 Japan The luminescence characteristics of Te- and Bi-doped glasses and glass-ceramics were investigated and the origin of coloration and near infrared luminescence was discussed. The colorations of these glasses and glass-ceramics might be due to the elemental clustering, such as Te 2 Te2 and Bi2 Bi2 . The broad near infrared NIR luminescence can be detected in Te- and Bi-doped glasses and glass-ceramics. The electron spin resonance ESR signal at 2.0 was observed in Te- and Bi-doped glasses and glass-ceramics, which exhibit NIR luminescence, and therefore this ESR signal is strongly related to the NIR luminescence. The ESR signal at