高固含量聚氨酯交联复合分散体的微观形态及流变行为及教材汇编.docVIP

高固含量聚氨酯交联复合分散体的微观形态及流变行为 张发兴1，卫晓利2，肖忠良1 （1中北大学太原 030051Morphology and Rheological Behaviorof High-solid Content Polyurethane Compound and Crosslinking Dispersions ZHANG Faxing1，WEI Xiaoli2，XIAO Zhongliang1 （1Department of science, North university of China, Taiyuan, 030051； 2Department of material and chemical engineering, Sichuan institute of technology ,Zigong, 643000） Abstract：A series of novel stable and high-solid-content polyurethane were prepared by self-emulsification, which were modified with γ-aminopropyl methyldimethyoxysilane (KH-550) as a blocking agent , the self-made silicon polyether (PES) and PPG as soft segments, TDI as hard segment, DHPS and DMPA as hydrophilic chain-extending agents. Influence of KH-550 content and mole ratio of PES/PPG on properties of polyurethane emulsions and films were analyzed .Results show that: the cross-linked complex were multivariate distribution in particle size and were spherical particles by measurement of grain size and electron microscopic photos.At the same time ,with an increase of the mass ratio of PES and PPG and content of KH-550 average particles diameter of polyurethane dispersions became bigger , poly-dispersion became wider., solid content of dispersions decrease, but also more than 45%. It is also noticed that the high-solid-content dispersions exhibit a pseudo-plastic behavior, when the mass ratio of PES and PPG is 1:3 and content of KH-550 is 1%, the solid content of dispersions is up to 55%. In addition, compared to pure polyurethane, stability characteristic of the dispersions decreased lightly at high temperature and low temperature as well as storage stability but which can meet the requirements basically. Key words：High-solid-content；Polyurethane dispersions；Compound and crosslinkingrheological behavior 联系人及第一作者：张发兴（1979—），男，博士研究生，讲师。 基金项目：山西省自然基金 Corresponding author: ZHANG Faxing, zfx1979228@163.com 引 言 高固含量水性聚氨酯HSLV-PU）与低固含量水性聚氨酯比较，主要有以下点：(1)固含量高，干燥快；(2)粘结性更强；(4)固含量任意稀释；(3)生产效率提高(企业中用于粘鞋，干燥快，生