Pt-Sn-Li／Al2O3／FeCrAl催化剂的制备、表征和长链烷烃脱氢催化性能.pdfVIP

第59卷 第 1期 化 工 学 报 Vol_59 NO．1 2008年1月 Journal of Chemical Industry and Engineering (China) January 2008 Pt—Sn—Li／Al2 O3／FeCrAl催化剂的制备、表征和 长链烷烃脱氢催化性能 卢泽湘，周忠良，银凤翔，季生福，刘 辉，李成岳 (北京化工大学化工资源有效利用国家重点实验室，北京 100029) 摘要：以FeCrA1合金薄片为基体，Pt_sn-Li／7一Alz0。为活性涂层，制备了Pt-sn_I i／A1。O。／FeCrA1金属基复合 载体负载型催化剂。采用XRD、SEM、TPR等手段对催化剂进行了表征，并在微型固定床反应器中考察了不同 反应温度、液时空速和氢／烃摩尔比下对长链烷烃脱氢的催化性能。结果表明，将活性浆料直接涂覆于焙烧后的 金属薄片上制得的催化剂有良好的结合性能，经超声波振荡后涂层脱落率小于2 。当Pt Sn-Li／7一A1 O。活性涂 层涂覆到FeCrA1金属基体后复合载体 AlzO。／FeCrA1与活性成分的相互作用明显增强。催化反应性能评价表明， 较高的反应温度有利于长链烷烃脱氢过程，但温度过高时将加速催化剂积炭失活。较低的空速有利于十二烷的 转化，但进一步减小空速将造成十二烯的选择性明显降低。减小氢／烃摩尔比虽然有利于提高十二烷的转化率， 但进一步减小氢／烃摩尔比也将加速催化剂积炭失活。 关键词：Pt-sl1-Li／Alz0。／FecrAl催化剂；金属基载体；长链烷烃 (十二烷)；脱氢；表征 中图分类号：0 643 文献标识码：A 文章编号：0438—1157(2008)O1—0070—07 Preparation and characterization of Pt—Sn—Li／AI2 03／FeCrAI catalyst and its catalytic performance for long chain alkane dehydr0genati0n LU Zexiang，ZHOU Zhongliang，YIN Fengxiang，jI Shengfu，LIU Hut，LI Chengyue (State Key Laboratory of Chemical Resources Engineering，Beijing University of Chemical Technology，Beijing 100029，China) Abstract：Pt～Sn-Li／A12 O3／FeCrA1 catalyst was prepared by using FeCrA1 alloy foil as the base of support and Pt—Sn-Li／)一Al2 03 as the active coating．The catalyst was characterized by means of XRD，SEM， H2-TPR．The effects of temperature，LHSV and the molar ratio of hydrogen to alkane on the catalytic performance for the long chain alkane dehydrogenation were investigated in a fixed—bed microreactor．The results indicated that the adhesiveness between support and active coating was very good，and only less than 2％ coating was peeled off after ultrasonic