循环灰对NH3氧化反应影响的试验研究.PDF

28 5 Vol.28 No.5 Feb.15, 2008 2008 2 15 Proceedings of the CSEE ©2008 Chin.Soc.for Elec.Eng. 57 0258-8013 (2008) 05-0057-06 TK 16 A 470 20 ⋅ NH 3 ( 100084) Experimental Study on the Effect of Circulating Ashes on Ammonia Oxidation HOU Xiang-song, CHANG Dong-wu, ZHANG Hai, YUE Guang-xi (Department of Thermal Engineering, Tsinghua University, Haidian District, Beijing 100084, China) ABSTRACT The de-NOx efficiency by ammonia injection in circulating fluidized bed (CFB) boiler is influenced by N2O ammonia catalytic oxidation over circulating ash. In order to assess the mechanisms of thermal de-NO in CFB boilers with 0 x ammonia (NH3) injection, the effect of circulating ashes on (circulating fluidized bed CFB) NH3 oxidation was experiment- ally studied. The experiments were conducted on a fixed bed reactor using quartz sand, circulating ash and its major component as bed materials. The NOx concentrations of NH , NO and N O in exhaust gas from the NOx 3 2 −6 −6 reactor were measured with Fourier transform infrared(FTIR). 50×10 150×10 N O