co0.7fe2.3o4纳米晶颗粒与薄膜的结构及磁性 structure and magnetic properties of nanocrystalline co0.7fe2.3o4 particles and thin films.pdfVIP

研究·分析·实验 Co Fe O 纳米晶颗粒与薄膜的结构及磁性 0.7 2.3 4 李 雁，方庆清，刘艳美，吕庆荣，尹 平 （安徽大学物理与材料科学学院，安徽省信息材料与器件重点实验室， 教育部光电信息获取与控制重点实验室，安徽合肥 230039 ） 摘 要：用化学共沉法制备了纳米 Co Fe O 粉末，用射频磁控溅射镀膜法制备了纳米结构的 Co Fe O 0.7 2.3 4 0.7 2.3 4 薄膜。采用 X 射线衍射仪及振动样品磁强计对不同热处理温度的样品进行了结构和磁性分析，结果显示， Co0.7Fe2.3O4 薄膜的比饱和磁化强度略低于粉体材料，矫顽力高于粉体材料，并且晶粒明显细化。650℃退火薄膜 具有最大矫顽力 -1 125.2 kA· m 。550℃退火薄膜可同时获得较高的矫顽力和较高的比饱和磁化强度。Co0.7Fe2.3O4 薄膜还具有平行膜面方向的择尤取向。 关键词：钴铁氧体纳米粉体；钴铁氧体薄膜；退火；微结构；磁性能 + 中图分类号：TM277 .1 献标识码：A 文章编号：1001-3830(2006)03-0028-03 Structure and Magnetic Properties of Nanocrystalline Co0.7Fe2.3O4 Particles and Thin Films LI Yan, FANG Qing-qing, LIU Yan-mei, LV Qing-rong, YIN Ping Department of Physics, Anhui University, Anhui Key Laboratory of Information Materials and Devices, Key Laboratory of Optoelectric Information Acquisition and Manipulation of the Ministry of Education, Hefei 230039, China Abstract: The nanocrystalline Co Fe O powders were synthesized by chemical co-deposition method, and 0.7 2.3 4 Co Fe O ferrite films with nanocrystalline structure were prepared by rf magnetron sputtering. The microstructure 0.7 2.3 4 and magnetic properties were analyzed and measured by X-ray diffraction (XRD), vibrating sample magnetometer (VSM). The experimental results show that the specific saturation magnetization of Co Fe