花状软锰矿的超声合成及其对亚甲基蓝的脱色性能.PDF

中国环境科学 2014,34(6) ：1435~1441 China Environmental Science 花状软锰矿的超声合成及其对亚甲基蓝的脱色性能 杨爱丽 1*,魏秉庆 2,张政军 1 (1.清华大学材料科学与工程学院,北京 100084 ；2.特拉华大学机械工程学院,美国 19716) 摘要：首次通过操作简便成本低廉的超声方法合成花状软锰矿(MWs).采用 X 射线衍射仪(XRD)、扫描电子显微镜(SEM) 以及能量散布分 析仪(EDS)等测试手段对其结构和形貌进行表征.研究了 MWs 对偶氮染料亚甲基蓝(MB)的脱色性能,考察 pH 值、反应时间、MWs 投加量 以及 MB 初始浓度等影响因子对脱色效果影响.结果表明,MWs 对 MB 具有优良的脱色性能,90min 达到近 100%的脱色率,无需使用 H2O2 或者 UV 灯和超声等其它辅助设备,这明显优于其他催化剂,如 Mn O /H O 需 3h 达到 99.7%最大脱色率、ZnS/CdS 在光照下需 6h 最大脱 3 4 2 2 色率仅为 73%、硫改性的 TiO2 光照下需 4h 才能达到近 100%的脱色率. 关键词：软锰矿(MWs) ；超声合成；表征；亚甲基蓝(MB) ；脱色 中图分类号：X703 文献标识码：A 文章编号：1000-6923(2014)06-1435-07 Ultrasonic synthesis of flower-like manganese wads and its decolorization performance for methylene blue. YANG 1* 2 1 Ai-li , WEI Bing-qing , ZHANG Zheng-jun (1.Department of Materials Science and Engineering, Tsinghua University, Beijing 100084, China ；2.Department of Mechanical Engineering, University of Delaware, Newark, DE 19716, USA). China Environmental Science, 2014,34(6)：1435~1441 Abstract ：Flower-like manganese wads (MWs) was synthesized via a simple and inexpensive ultrasonic method for the first time. The structure and morphology of MWs were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive spectrometer (EDS). The decolorization efficiencies of MWs for azo dye methylene blue (MB) were examined as a function of solution pH, stirring time, MWs dosage, and initial MB concentration. Results showed that MWs had higher decolorization efficiency (the maximum decolorization rate of nearly 100% in 90min) than other catalysts, such as Mn O /H O (the maximum decolorization rate of 99.7% in 3h), ZnS/CdS