electrooxidation of hydrogen on ni-organic metal complex catalysts in acidic media for pemfcs电氧化氢的ni-organic对质子交换膜燃料电池金属络合物催化剂在酸性介质.pdfVIP

Hindawi Publishing Corporation Journal of Nanomaterials Volume 2011, Article ID 532926, 9 pages doi:10.1155/2011/532926 Research Article Electrooxidation of Hydrogen on Ni-Organic Metal Complex Catalysts in Acidic Media for PEMFCs Rui Lin,1 Jinli Qiao,2 Haiyan Zhang,3 Chunhui Cao,1 Jing Fu,3 and Jianxin Ma1 1 Clean Energy Automotive Engineering Center School of Automotive Studies, Tongji University, Shanghai 201804, China 2 College of Environmental Science and Engineering, Donghua University, Shanghai 201620, China 3 School of Resource and Environmental Engineering, East China University of Science and Technology, Shanghai 200237, China Correspondence should be addressed to Jinli Qiao, qiaojl@ and Jianxin Ma, jxma@ Received 23 March 2011; Accepted 9 May 2011 Academic Editor: Zhenmeng Peng Copyright © 2011 Rui Lin et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. Novel organic metal complexes with N2 O2 coordination structure which showed high hydrogen oxidation reaction were synthe- sized. The catalytic activity was found to strongly depend on the heat-treatment temperature and the structural properties. 1. Introduction Ru-based binary catalysts [18–23], macrocycles (porphyrin or phthalocyanine), and nonprecious metal catalysts [24– Proton exchange membrane fuel cells (PEMFCs) are consid- 27]. ered to be one of the most promising future energy powers. Though it is important to learn oxygen reduction reac- Despite many efforts have been devoted to the development