contribution to a comparative study of the corrosion inhibiting effect of some azoles, to protect the cu70-30ni alloy in aerated nacl 3% in presence of ammonia贡献的腐蚀抑制作用的比较研究一些唑类,在充气保护cu70-30ni合金氯化钠3%氨的存在.pdfVIP

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contribution to a comparative study of the corrosion inhibiting effect of some azoles, to protect the cu70-30ni alloy in aerated nacl 3% in presence of ammonia贡献的腐蚀抑制作用的比较研究一些唑类,在充气保护cu70-30ni合金氯化钠3%氨的存在.pdf

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contribution to a comparative study of the corrosion inhibiting effect of some azoles, to protect the cu70-30ni alloy in aerated nacl 3% in presence of ammonia贡献的腐蚀抑制作用的比较研究一些唑类,在充气保护cu70-30ni合金氯化钠3%氨的存在

Materials Sciences and Applications, 2011, 2, 276-283 doi:10.4236/msa.2011.24036 Published Online April 2011 (/journal/msa) Contribution to a Comparative Study of the Corrosion Inhibiting Effect of Some Azoles, to Protect the Cu70-30Ni Alloy in Aerated NaCl 3% in Presence of Ammonia 1,3 1,2, 3 1 2 Mohammed Benmessaoud , Karima Es-salah , Ahmed Kabouri , Najjat Hajjaji , Hisai Takenouti , Abdelah Srhiri1 1Laboratory of Electrochemistry, Materials and Environment (LEME), Faculty of Sciences, Ibn Tofail University, Kenitra, Morocco; 2CNRS UPR 15, LISE, UPMC University, Paris, France; 3University of Mohammed V Agdal, Energy Systems Laboratory, Materials and Environment, High School of Technology, Salé Medina, Morocco E-mail: benmessaoud_mma@yahoo.fr Received November 20th, 2010; revised January 17th, 2011; accepted March 11th, 2011. ABSTRACT Some azoles were tested such as 3-amino- 1,2,4-triazole (ATA), 3-4’-bitriazole -1,2,4 (BiTA)and 2-Mercaptobenzimi- dazole (MBI) against Cu-30Ni alloy corrosion in 3%NaCl polluted by ammonia using potentiodynamic measurements and electrochemical impedance spectroscopy and non-electrochemical techniques (scanning Electron Microscopy (SEM)) studied surface morphology has been used to characterize electrode surface. This study permitted to follow the evolution of the inhibitory effect of some azoles, on Cu-30Ni alloy corrosion in 3% NaCl polluted by ammonia and in- dicate that the tested inhibitors act as a good mixed-type inhibitor retarding the anodic and cathodic reactions. An in- crease of the inhibitors concentration leads to a decrease of corrosion rate and inhibition efficiency increase. Keywords : Cu-30Ni Alloy, Electrochemical Impedance Spectroscopy, Ammonia, Inhibition, Azole 1. Introduction