dielectric spectroscopy of diglycidyl ether of bisphenol-a at glass transition temperature介电谱的缩水甘油醚双酚a在玻璃化转变温度.pdfVIP

Vol.4, No.2, 136-141 (2012) Natural Science /10.4236/ns.2012.42020 Dielectric spectroscopy of diglycidyl ether of bisphenol-A at glass transition temperature Soheil Sharifi Department of Physics, University of Sistan and Baluchestan, Zahedan, Iran; soheil.sharifi@ Received 29 December 2011; revised 20 January 2012; accepted 8 February 2012 ABSTRACT pected for intermolecular secondary relaxations [1-3], ori- ginated by local motions of the entire molecule. These We used broadband dielectric spectroscopy in –2 7 processes, possibly relevant for the glass transition, are the frequency range from 10 Hz up to 10 Hz now referred to as the Johari-Goldstein (JG) secondary and we found dynamics of the primary - and in- or JG -relaxation to honor their discovery of secondary termolecular Johari-Goldstein (JG) -processes relaxation even in totally rigid molecules without internal are strongly correlated in diglycidyl ether of bis- degree of freedom. A rational of relaxation dynamics in phenol-A over a wide temperature from 193 to such terms is for example proposed by the Coupling Mo- 283K and pressure P range from 0.1 to 600 MPa. del [4]. Analysing the temperature and pressure beha- In this paper we contribute to such discussion by in- vior of the - and (JG) -processes, a clear corre- vestigating the relation between the structural and the JG lation has been found between the structural re-