dielectric spectroscopy of pvac at different isobaric-isothermal paths介电谱的pvac isobaric-isothermal路径不同.pdfVIP

Materials Sciences and Applications, 2012, 3, 168-172 /10.4236/msa.2012.33026 Published Online March 2012 (http://www.SciRP.org/journal/msa) Dielectric Spectroscopy of PVAc at Different Isobaric-Isothermal Paths Soheil Sharifi Department of Physics, University of Sistan and Baluchestan, Zahedan, Iran. Email: soheil.sharifi@, sharifi@df.unipi.it Received December 30th, 2011; revised January 29th, 2012; accepted February 29th, 2012 ABSTRACT We studied broadband dielectric spectroscopy of a glass from systems that the dynamics of the primary - and the Johari-Goldstein (JG) -processes are strongly correlated in Poly(vinyl acetate) over a wide temperature T and pressure P range. Analysing the temperature and pressure behaviour of the - and (Non-JG) -processes, a correlation hasnot been found between the structural relaxation time, the (Non-JG) -processes relaxation time and the dispersion of the structural relaxation. These results support the idea that the (JG)-processes relaxation acts as a precursor of the structural relaxation and therefore of the glass transition phenomenon but it isnot clear relation in the (Non-JG) - processes and structural relaxation at PVAc . Keywords: Dielectric Relaxation; Nan-Size Motion; Pressure and Temperature 1. Introduction secondary processes in the poly (vinyl acetate) (PVAc) in an interval of pressure ranging from 0.1 to 600 MPa and Usually in the Glass former materials we can find com- temperature from 100 to 350 K. The main goal is to find plex relaxation pattern, which evolves over several time relation between alpha and second