effect of camphor sulfonic acid doping on structural, morphological, optical and electrical transport properties on polyaniline-zno nanocomposites樟脑磺酸掺杂对结构的影响,形态、光学和电子传输polyaniline-zno纳米复合材料上的属性.pdfVIP

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effect of camphor sulfonic acid doping on structural, morphological, optical and electrical transport properties on polyaniline-zno nanocomposites樟脑磺酸掺杂对结构的影响,形态、光学和电子传输polyaniline-zno纳米复合材料上的属性.pdf

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effect of camphor sulfonic acid doping on structural, morphological, optical and electrical transport properties on polyaniline-zno nanocomposites樟脑磺酸掺杂对结构的影响,形态、光学和电子传输polyaniline-zno纳米复合材料上的属性

Soft Nanoscience Letters, 2012, 2, 46-53 /10.4236/snl.2012.23009 Published Online July 2012 (http://www.SciRP.org/journal/snl) Effect of Camphor Sulfonic Acid Doping on Structural, Morphological, Optical and Electrical Transport Properties on Polyaniline-ZnO Nanocomposites 1 1 1 2 1* Sanjay L. Patil , Manik A. Chougule , Shailesh G. Pawar , Shashwati Sen , Vikas B. Patil 1Materials Research Laboratory, School of Physical Sciences, Solapur University, Solapur, India; 2Crystal Technology Section, Techni- cal Physics Division, Bhabha Atomic Research Centre (BARC), Mumbai, India. * Email: drvbpatil@ Received April 17th, 2012; revised May 24th, 2012; accepted June 4th, 2012 ABSTRACT In the present work, we report on effect of camphor sulfonic acid (CSA) doping on polyaniline-ZnO (50%) nanocompo- sites prepared by spin coating method on glass substrates. The XRD analysis revealed that the addition of CSA has no effect on crystallinity of PANi-ZnO nanocomposites. Surface morphological studies (SEM) showed that CSA has a strong effect on morphology of PANi-ZnO. The FTIR UV-Vis spectroscopy confirmed the interaction between CSA and PANi-ZnO nanocomposite. DC electrical conductivity studies showed an increase in conductivity of PANi-ZnO nanocomposites by one order due to addition of CSA (10% - 50%). Keywords: Polyaniline; Zinc Oxide; XRD; SEM; FTIR; UV-Vis 1. Introduction ronmental stability [15,16] and tunable conductivity. Several reports on the synthesis of composite of nano- Semiconducting zinc oxide (ZnO) is attracting lot of at- +