effect of thermoplastic incorporation on the performance of thermosetting matrix热塑性的影响公司在热固性基体的性能.pdfVIP

Materials Sciences and Applications, 2012, 3, 442-447 /10.4236/msa.2012.37062 Published Online July 2012 (http://www.SciRP.org/journal/msa) Effect of Thermoplastic Incorporation on the Performance of Thermosetting Matrix * R. Ollier, A. Stocchi, E. Rodriguez, V. Alvarez Composite Materials Group, Materials Science and Technology Research Institute (INTEMA), University of Mar del Plata—Na- tional Research Council (CONICET), Mar del Plata, Argentina. * Email: alvarezvera@.ar th th st Received January 29 , 2012; received March 10 , 2012; accepted May 1 , 2012 ABSTRACT In this work, the morphology, thermal and viscoelastic properties, deformation and fracture behaviour of a commercial vinylester resin modified with a biodegradable polymer was investigated. Flexural, impact and fracture tests were per- formed on the blends with different polycaprolactone (PCL) contents. They exhibited improved stiffness and fracture properties in comparison to the neat resin. From SEM analysis of fracture surfaces, stress whitening and branced frac- ture paths toughening mechanisms were identified. The dependence of the glass transition temperature with PCL con- tent was adequately fitted by simple models available in the literature. From the results of these models along with the results of calorimetric studies and SEM analysis, it can be concluded that the interaction between vinylester and PCL is strong enough to avoid phase separation. Keywords: Polymer Matrix Composites; Mechanical Properties; Fracture 1. Introduction compared with rubbers [6]. Various types of thermoplas- tics have been explored in order to modify thermose