原创力文档effect of chromium on the corrosion behavior of powder-processed fe-0.6 wt % p alloys铬对powder-processed铁的腐蚀行为的影响- 0.6 wt % p合金.pdfVIP
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effect of chromium on the corrosion behavior of powder-processed fe-0.6 wt % p alloys铬对powder-processed铁的腐蚀行为的影响- 0.6 wt % p合金
Journal of Minerals and Materials Characterization and Engineering, 2012, 11, 908-913
Published Online September 2012 (http://www.SciRP.org/journal/jmmce)
Effect of Chromium on the Corrosion Behavior of
Powder-Processed Fe-0.6 wt% P Alloys
*
Yashwant Mehta , Shefali Trivedi, K. Chandra, P. S. Mishra
Indian Institute of Technology, Roorkee, Uttarakhand, India
*
Email: yashwant.mehta@
Received June 7, 2012; revised August 18, 2012; accepted September 11, 2012
ABSTRACT
Phosphoric irons (i.e. Fe-P alloys containing low phosphorous in the range 0.1 to 0.7 wt%) with/without addition of
chromium were prepared by powder forging route. The corrosion behaviour of these alloys was studied in different en-
vironments. The various environments chosen were acidic (0.25 M H SO solution of pH 0.6), neutral/marine (3.5%
2 4
NaCl solution of pH 6.8) and alkaline (0.5 M Na CO + 1.0 M NaHCO solution of pH 9.4). The corrosion studies were
2 3 3
conducted using Tafel Extrapolation and Linear Polarization techniques. The results were compared with the corrosion
resistance of electrolytic Armco iron. It was observed that, chromium improved the resistance to corrosion in marine
conditions only. Corrosion rates were higher in acid medium due to the enhanced hydrogen evolution and hence, the
cathodic reaction. The corrosion rates were minimal in alkaline medium and low in neutral solution.
Keywords: Phosphoric Iron; Alloy; Polarization; Acid Corrosion; Alkaline Corrosion
1. Introduction
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