.实验4_液体饱和蒸汽压的测定.pdfVIP

娑蹭綋楗卞拰钂告皵鍘嬬殑娴嬪畾 1 寮曡█ 1.1 瀹為獙鐩殑 (1) 杩愮敤 Clausius-Clapeyron 鏂圭▼锛屾眰鍑烘墍娴嬫俯搴﹁寖鍥村唴鐨勬恫浣撳钩鍧囨懇灏旀苯鍖栫創鍙 姝ｅ父娌哥偣 (2) 鎺屾彙娴嬪畾楗卞拰钂告皵鍘嬬殑鏂规硶 1.2 瀹為獙鍘熺悊 娑蹭綋鐨勮捀姘斿帇涓庢恫浣撶殑鏈€т互鍙婃俯搴︽湁鍏炽€傛俯搴﹀崌楂樻椂锛屾恫浣撳垎瀛愬钩鍧囧姩鑳藉澶э紝 钂告皵鍘嬩笂鍗囷紝鍙嶄箣浜︾劧銆傚綋娑蹭綋鍦ㄥ叾娓╁害涓嬬殑钂告皵鍘嬬瓑浜庡鐣屽帇鍔涙椂锛屾恫浣撴哺鑵撅紝 杩欎釜娓╁害绉颁负娑蹭綋鐨勬哺鐐广€傚湪澶栧帇涓吼€仢鈯 = 101.325 kPa涓嬫恫浣撶殑娌哥偣绉颁负鏍囧噯娌哥偣銆 娑蹭綋鐨勯ケ鍜岃捀姘斿帇涓庢俯搴︾殑鍏崇郴鐢盋lausius-Clapeyron 鏂圭▼缁欏嚭锛 ( ) 螖 饊€ d ln 饊仢 vap 饊仛 = d饊亣 饊亝饊亣2 寮忎腑R 涓烘懇灏旀皵浣撳父鏁帮紱T 涓虹儹鍔涘娓╁害锛屛攙ap 饊€火€仛 鏄俯搴 涓嬬函娑蹭綋鐨勬懇灏旀苯鍖 鐑€ 鍋囧畾螖vap 饊€火€仛 涓庢俯搴︽棤鍏筹紝瀵逛笂寮忕Н鍒嗭紝鍙緱 螖 饊€ ln 饊仢 = 鈭 vap 饊仛 + 戆 饊亝饊亣 鑻ュ皢ln 饊仢瀵?/饊亣浣滃浘锛屽簲璇ュ緱鍒颁竴鏉＄洿绾匡紝鏂滅巼饊仛 = 鈭捨 饊€ /饊亝 锛屼簬鏄 vap 饊仛 螖 饊€ = 鈭掟€亝饊仛 vap 饊仛 鍦ㄤ笉鍚屾俯搴︿笅娴嬪畾绾恫浣撶殑楗卞拰钂告皵鍘嬶紝鍙互鎺ㄥ嚭璇ユ恫浣撶殑鎽╁皵姹藉寲鐒撳拰姝ｅ父娌 鐐逛簡銆 2 瀹為獙鎿嶄綔 2.1 瀹為獙鐢ㄥ搧銆佷华鍣ㄥ強瑁呯疆 瀹為獙浣跨敤绛夊帇绠? 鏀紝绋冲帇鐡? 涓紝璐熷帇鐡? 涓紝鎭掓俯妲? 濂楋紝鐪熺┖娉? 鍙帮紝骞茬嚗 绠′竴濂楋紝鎼呮媽鍣ㄤ竴鍙帮紝鍘嬪姏璁? 鍙帮紝鏁版樉娓╁害浠€ 涔欓唶 锛圓R 锛 娴嬭瘯瑁呯疆濡傚浘2.1 鎵€绀 锛堝疄楠屼腑浣跨敤鏁版樉娓╁害浠級 鍥?.1 2.2 瀹為獙鏉′欢 瀹為獙杩囩▼涓疄楠屽鍐呮俯搴?9.3 掳C锛岀浉瀵规箍搴?0%锛屽ぇ姘斿帇102.15 kPa 2.3 瀹為獙鎿嶄綔 (1) 瑁呯疆涓庤鏍枫€傛姝ラ宸插湪璇惧墠瀹屾垚锛 (2) 妫€婕忋€傚皢H 娲诲鍏充笂锛屾墦寮€娲诲I銆丗 鍜孏锛岀敤鐪熺┖娉垫娊姘斿埌鍘嬪姏璁℃樉绀虹殑姘 鍘嬩负25kPa 鏃讹紝鍏抽棴I銆丗 鍜孏 銆傜瓑鐗囧埢鍚庯紝鑻ュ帇鍔涜鏁颁笉鍙樿鏄庣郴缁熸皵瀵嗘€ц壇 濂斤紱 (3) 鍗囨俯銆傚紑鍔ㄦ悈鎷屽櫒锛岃皟鑺傚姞鐑櫒鐢靛帇鍦?60V 宸﹀彸锛 (4) 鎺掓皵銆傚綋姘存荡娓╁害瓒呰繃50 掳C 鏃讹紝绛夊帇绠″唴娑蹭綋寮€濮嬫哺鑵撅紝澶ч噺姘旀场鐢盋 绠℃帓 鍑恒€傛哺鑵?~5 min 灏卞彲浠ラ櫎鍘籄B 闂寸殑绌烘皵鍙婃憾鍦ㄦ恫浣撲腑鐨勭┖姘斻€傛敞鎰忚皟鑺傚姞 鐑櫒鐢靛帇锛屾帶鍒舵亽娓╂Ы娓╁害鍦?0 掳C 闄勮繎锛 (5) 钂告皵鍘嬬殑娴嬪畾銆傛帓