黔西南高砷煤热解过程中微量元素释放规律研究.PDF

中国环境科学 2011,31(12) ：2005~2012 China Environmental Science 黔西南高砷煤热解过程中微量元素释放规律研究 魏晓飞 1,2,张国平 1*,李 玲 1,项 萌 1,2,蔡永兵 1,2 (1. 中国科学院地球化学研究所,环境地球化学国家重点实 验室,贵州 贵阳 550002 ；2. 中国科学院研究生院,北京 100049) 摘要：采用高温箱式电阻炉对黔西南海子地区煤样进行热解,研究了在 300~1200℃下慢速热解过程中,热解温度、元素赋存状态和灰分对 微量元素释放规律的影响.结果表明,热解温度是影响煤失重和微量元素挥发的主要原因. As、Mo 在 900℃以上挥发较快; Pb 热解前期挥发 较快,450℃以上挥发缓慢;Sb 随热解温度的升高缓慢增大.微量元素的挥发性还与赋存状态关系密切,有机态最为活泼;硫化物态和碳酸盐 态在热解后期由于矿物的分解而逐步释放;硅酸盐态最稳定,基本残留在灰分中.灰分越高微量元素越不易挥发. 关键词：黔西南煤；热解；微量元素；挥发性；赋存状态 中图分类号：X502 文献标识码：A 文章编号：1000-6923(2011)12-2005-08 Volatility of trace elements during pyrolysis of high arsenic coal from southwestern Guizhou. WEI Xiao-fei1, 2, ZHANG Guo-ping1* 1 1,2 1,2 , LI Ling , XIANG Meng , CAI Yong-bing (1.State Key Laboratory of Environmental Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550002, China；2.Graduate University of Chinese Academy of Sciences, Beijing 100049, China). China Environmental Science, 2011,31(12)：2005~2012 Abstract ：Pyrolysis experiments were carried out in a box resistance reactor at 300~1200 ℃ to evaluate the volatility of trace elements in the coal from southwestern Guizhou. The impact of pyrolysis temperature, mode of element occurrence and ash content of coal on trace elements release were investigated. Coal weight loss and trace element volatility were primarily affected by pyrolysis temperature. As and Mo showed an strong release when temperature was higher than 900 ℃. Pb showed a high volatility at the early stage of pyrolysis( 450℃), and then a lower volatility when temperature was over 450℃. With the increase of pyrolysis temperature, the volatility of Sb increased gradually. The volatility of trace elements showed a close correlation with the mode of element occurrence. Trace element of organic pha