添加剂对双子表面活性剂DYNOL_604浊点的影响.pdfVIP

2002 年第 60 卷 化 学 学 报 Vol. 60 , 2002 第 5 期 , 810～814 ACTA CHIMICA SINICA No. 5 , 810 ～814 添加剂对双子表面活性剂 DYNOL604 浊点的影响 陈文君　　顾　强　　姚发业　　李干佐 ( 山东大学胶体与界面化学教育部重点实验室 　济南 250100) 摘要 　对双子表面活性剂 DYNOL604 的浊点开展研究 ,考察了添加剂对其浊点的影响. 离子表面活性剂的加入 ,使 其浊点升高 ,而加入醇时出现了一种双浊点的现象 ,我们称之为“下限浊点”和“上限浊点”. 即温度低于“下限浊点” 和高于“上限浊点”,体系由浑浊变为澄清. 采用 NMR 手段测定“上限浊点”以上温度体系的自扩散系数 ,证明为双连 续微乳液结构 ,并从 R 比值理论进行分析. 关键词 　DYNOL604 ,双浊点 ,下限浊点 ,上限浊点 ,添加剂 , 自扩散系数 Effect of Alcohol and IonSurfactant on the Cloud Point of Dynol604 CHEN , WenJun 　　GU , Qiang 　　YAO , FaYe 　　LI , GanZuo ( ) Key Lab for Colloid and Interface Chemistry of State Education Ministry , Shandong University , Jinan 250100 Abstract 　The effect of a series of alcohols and ionic surfactants on the cloud point (CP) of nonionic surfactant Dynol604 has been investigated. The result shows that the addition of SDS and CTAB makes the cloud point of Dynol604 increases greatly and the influence of alcohols on the cloud point of Dynol604 is complex. When the alcohol is added into the Dynol604 solution , the system appears double cloud points which are named “upper limit CP”and “lower limit CP”respectively. The phenomenon is discussed using the theory of Cohesion Energy Ratio. The system becomes transparent from turbidity when the temperature is above the upper limit CP. The measurement of the selfdiffusion coefficients by