ZnO表面处理对光催化还原CO2性能的影响.docVIP

ZnO表面处理对光催化还原CO2性能的影响 摘要：通过一个简单的氧化还原路线，对ZnO进行不同程度的表面处理。随后对经过表面处理的氧化锌材料的形貌、表面结构、粒径大小等特性进行了表征。，分别是X射线衍射，N 2物理吸附测量，紫外可见，PL光谱，SEM，TEM和二氧化碳吸附的FTIR。表征结果证实，表面处理后所得的ZnO复合材料具有高比表面积，能减小光的吸附能力，并且不会影响晶体结构的优点。通过反应性能和CO2-FTIR发现，适当的表面氧化处理可以有效地促进CO2吸附和增强生成的b-CO32-中间体，调高H2O2浓度后ZnO催化剂的甲烷产量是纯的ZnO催化剂的上百倍。同时，延长反应时间，ZnO催化剂更偏向于CO2和H2O混合选择性生成CH3OH。可能是由于电子迅速分离传送到催化材料表面的OH基团，这直接关系到甲醇的产量。12782 关键词：氧化锌;二氧化碳光催化;二氧化碳吸附中间体;表面处理 Effect of ZnO surface treatment on photocatalytic reduction of CO2 Abstract: Through a simple redox route, the ZnO were treated with different degrees of surface treatment. The morphology, surface structure, particle size and other characteristics of the surface treated Zinc Oxide were characterized. X ray diffraction, N 2 physical adsorption measurements, UV Vis, PL spectroscopy, SEM, TEM and carbon dioxide adsorption of FTIR. Characterization results show that the surface treatment of the resulting ZnO Composite with high specific surface area, can reduce the adsorption capacity of Hikari and will not affect the crystal structure of the advantages. Appropriate surface oxidation treatment can effectively promote adsorption of CO2 and enhanced generation of b-CO32- intermediates, adjustable high H2O2 concentration ZnO catalyst for methane production is a hundred times more than that of the pure ZnO catalyst, found through the reaction performance and CO2-FTIR. At the same time, increasing the reaction temperature, ZnO catalyst is more inclined to the CO2 and H2O mixed selective generation CH3OH. May be due to the rapid separation of electrons transferred to the catalytic material surface of the OH group, which is directly related to the production of methanol. 3.3透射电镜(TEM)和高分辨率透射电镜图(HRTEM)分析12 3.4紫外可见漫反射光谱分析(UV-VISIBLE)12 3.5光致发光光谱分析( PL)13 3.6原位红外光谱谱图分析(IN SITU DRIFT SPECTRA)13 3.7CO2光催化性能测试14 3.8CO2光还原与水的机理14 致谢18 参考文献19 附录21 1.文献综述 1.1研究的意义 随着人类的活动日益频繁，对能源需求量的不断攀升，全球工业化发展带来全球的CO2的排放量急剧增加，由此产生的环境问题日益严重。根据政府间气候变化专门委员会(IPCC)颁布的第四次气候变化评估报告[1]，1970年-2004年全球室温气体的排放量增长