年产15万吨甲醇低压羰基化合成醋酸工艺设计.doc

年产15万吨甲醇低压羰基化合成醋酸工艺设计 设计说明 醋酸是重要的基础化工原料之一，主要用于生产醋酸乙烯单体、酸酐、聚乙烯醇、醋酸纤维素等，广泛应用于化工、医药、合成纤维、化工、纺织皮革、农药、炸药、橡胶、金属加工、食品以及精细有机合成等行业.它对国民经济的许多部门具有重要作用，是近几年世界上发展较快的有机化工产品之一。随着低压法甲醇羰基化制醋酸和酸酐工业化的发展，一种可以完全不依赖于石油，以醋酸和酸酐及其衍生物为原料的新一代煤化工路线日益受到人们的重视。本是对甲醇低压羰基化合成醋酸进行工艺设计，根据考察及参考资料，对甲醇低压羰基化合成醋酸的工艺流程进行了全面设计。设计的范围包括：工艺流程设计、工艺计算、主要设备选型、车间布置设计，以及工艺流程图和各个设备图的绘制9142 关键词： 甲醇；羰基化合；醋酸 Annual output of 150000 tons of low pressure methanol carbonyl synthesis of acetic acid process design Abstract: Acetic acid is one of the important basic chemical raw materials, mainly for the production of vinyl acetate monomer,anhydride, polyvinly alcohol, acetic acid cellulose etc., are widely used in chemical industry, medicine, synthetic fiber, chemical, textile, leather, pesticide, explosive, rubber, metal processing, food and fine organic synthesis industry. It plays an important role in many departments of national economy. And it is one of the rapid development of organic chemical products in the world in recent years. With the development of low pressure methanol carbonyl method acetic acid and anhydride industrial, a new generation of coal chemical industry which will completely not rely on oil, acetic acid and anhydride and its derivatives as the raw material is increasingly attracting the attention of people. This paper is carried out on the low pressure methanol carbonyl synthesis of acetic acid process design. According to the investigation, and resources, low carbonyl synthesis of acetic acid to methanol process has carried on the comprehensive design. The scope of the design include: process design, process, main equipment selection, shop layout design, and process flow diagram and the drawing of the graph of each device 3.2.1 所处理的物料带到设备中去的热量 13 3.2.2过程的热效应：14 3.2.3反应产物由设备中带出的热量 16 3.2.4设备向四周散失的热量 17 3.2.5消耗在加热设备各个部件上的热量 17 4 醋酸精馏塔计算17 4.1 精馏塔的选择18 4.2 精馏塔的设计18 4.2.1 基础数据整理18 4.2.2 初估塔径19 4.2.3 理论板数的计算21 4.2.4 塔内件设计24 4.2.5 塔板流体力学验算27 4.2.6 塔板负荷性能图29 4.2.7 醋酸精制塔工艺计算结果汇总32 5 部分设备选型与计算34 5.1