十四烷基芳基磺酸盐在大庆油砂上的吸附性能-IngentaConnect.PDF

物理化学学报(Wuli Huaxue Xuebao) December Acta Phys. -Chim. Sin . 2011, 27 (12), 2767-2772 2767 [Article] doi: 10.3866/PKU.WHX 十四烷基芳基磺酸盐在大庆油砂上的吸附性能 董志龙 丁 伟* 刘 坤 张志伟 曲广淼 于 涛 (东北石油大学化学化工学院, 黑龙江大庆163318) 摘要: 利用静态吸附实验研究了实验室自制的三种高纯度十四烷基芳基磺酸盐在大庆油砂上的吸附规律, 并 考察了吸附时间, 吸附温度及磺酸盐、NaCl、NaOH、正丁醇的浓度对吸附量的影响. 结果表明: 吸附量随着磺酸 盐浓度的增大逐渐增加后趋于平稳, 随着吸附温度和正丁醇体积浓度的降低、NaCl 和NaOH 浓度的增加而增 大; 磺酸盐活性剂的三种同分异构体中, 随两部分碳链长度趋于均等, 吸附量下降, 且受助剂的影响变小. 吸附 热力学研究表明, 十四烷基芳基磺酸盐在油砂上的吸附等温线服从Langmuir 等温方程, 并且计算得到的各参 数均能很好地反映磺酸盐在油砂上的吸附特征. 吸附动力学研究表明, Elovich 方程能够更好地描述吸附量随 时间的变化情况. 关键词: 烷基芳基磺酸盐; 助剂; 固/液吸附; 吸附热力学; 吸附动力学 中图分类号: O642; O643 Adsorption Performance of Tetradecyl Aryl Sulfonates on Oil Sand from the Daqing Oilfield DONG Zhi-Long DING Wei* LIU Kun ZHANG Zhi-Wei QU Guang-Miao YU Tao (Chemistry and Chemical Engineering School, Northeast University of Petroleum, Daqing 163318, Helongjiang Province, P. R. China) Abstract: Three tetradecyl aryl sulfonates of high purity were synthesized. Their static adsorption performance on oil sand from the Daqing oilfield was studied and the influence of adsorption time, adsorption temperature, concentrations of sulfonate, NaCl, NaOH, and n-butyl alcohol on the efficiency of adsorption were investigated. The experimental results show that with an increase in the concentrations of the sulfonates the adsorption capacity initially increased and then remained constant. The adsorption capacity