selective electrocatalytic hydrogenation of linolenic acid on and catalysts亚麻酸的选择性electrocatalytic加氢催化剂.pdfVIP

SAGE-Hindawi Access to Research International Journal of Electrochemistry Volume 2011, Article ID 485194, 9 pages doi:10.4061/2011/485194 Research Article Selective Electrocatalytic Hydrogenation of Linolenic Acid on Pd/Al O and Pd-Co/Al O Catalysts 2 3 2 3 1 1 ´ ´ 2 ´ 2 Sylvie Breton, Anne Brisach-Wittmeyer, Jose Julian Rios Martın, Manuel Leon Camacho, 1 ´ 1 Andrzej Lasia, and Hugues Menard 1 Universite de Sherbrooke, 2500 Boulevard de l’Universite, Sherbrooke , Quebec, Canada J1K 2R1 ´ ´ ´ 2 Instituto de la Grasa, CSIC (Consejo Superior de Investigaciones Cientificas), Avenida Padre Garcıa Tejero, 4. 41012 Sevilla, Spain ´ Correspondence should be addressed to Anne Brisach-Wittmeyer, anne.wittmeyer@usherbrooke.ca Received 5 July 2010; Revised 19 October 2010; Accepted 22 November 2010 Academic Editor: Shen-Ming Chen Copyright © 2011 Sylvie Breton et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. Electrochemical hydrogenation of linolenic acid as a model for polyunsaturated acids was studied on Pd and Pd/Al2 O3 catalysts in acidic and alkaline media. The results are presented in terms of number of double bonds in the polyunsaturated